Effects of hyperthermal atomic oxygen on a cyanate ester and its carbon fiber-reinforced composite
文献类型：期刊论文
| 作者 | Wang, Heilong6,7; Qian, Min4; Murray, Vanessa J.1; Wu, Bohan5; Yang, Yang3; Dong, Aiyi2; Che, Li2,6; Minton, Timothy K.1 |
| 刊名 | HIGH PERFORMANCE POLYMERS
 |
| 出版日期 | 2019-05-01 |
| 卷号 | 31期号:4页码:472-482 |
| 关键词 | Cyanate ester carbon fiber atomic oxygen low Earth orbit |
| ISSN号 | 0954-0083 |
| DOI | 10.1177/0954008318788401 |
| 通讯作者 | Wu, Bohan(bohanwoo@hotmail.com) ; Che, Li(liche@dlmu.edu.cn) ; Minton, Timothy K.(tminton@montana.edu) |
| 英文摘要 | The durability of cyanate ester (CE) to hyperthermal atomic oxygen (AO) attack in low Earth orbit may be enhanced by the addition of carbon fiber to form a carbon fiber-reinforced cyanate ester composite (CFCE). To investigate the durability of CFCE relative to CE, samples were exposed to a pulsed hyperthermal AO beam in two distinct types of experiments. In one type of experiment, samples were exposed to the beam, with pre- and post-characterization of mass (microbalance), surface topography (scanning electron microscopy (SEM)), and surface chemistry (X-ray photoelectron spectroscopy (XPS)). In the second type of experiment, the beam was directed at a sample surface, and volatile products that scattered from the surface were detected in situ with the use of a rotatable mass spectrometer detector. CFCE exhibited less mass loss than pure CE with a given AO fluence, confirming that the incorporation of carbon fiber adds AO resistance to CE. Erosion yields of CE and CFCE were 2.63 +/- 0.16 x 10(-24) and 1.46 +/- 0.08 x 10(-24) cm(3) O-atom(-1), respectively. The reduced reactivity of CFCE in comparison to CE was manifested in less oxidation of the CFCE surface in XPS measurements and reduced CO, CO2, and OH reaction products in beam-surface scattering experiments. The surface topographical images collected by SEM implied different surface deterioration processes for CE and CFCE. A change of surface topography with increasing AO fluence for CE indicated a threshold AO fluence, above which the erosion mechanism changed qualitatively. CFCE showed almost intact carbon fibers after relatively low AO fluences, and while the fibers eventually eroded, they did not erode as rapidly as the CE component of the composite. |
| WOS关键词 | HIGH DIELECTRIC-CONSTANT ; SCATTERING DYNAMICS ; SPACE ENVIRONMENT ; POLYMERS ; RESISTANCE ; EROSION ; GRAPHITE ; DURABILITY ; DEPOSITION ; POLYIMIDE |
| 资助项目 | National Science Foundation of China[21473015] ; National Science Foundation of China[21203016] ; National Science Foundation of China[41574101] ; National Excellent Doctoral Thesis Author Special Fund Project[201222] ; Fundamental Research Funds for the Central Universities[3132018233] ; Fundamental Research Funds for the Central Universities[3132018232] ; Shanghai Sailing Program[17YF1403300] |
| WOS研究方向 | Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000462336400011 |
| 出版者 | SAGE PUBLICATIONS LTD |
| 资助机构 | National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program ; National Science Foundation of China ; National Science Foundation of China ; National Excellent Doctoral Thesis Author Special Fund Project ; National Excellent Doctoral Thesis Author Special Fund Project ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Shanghai Sailing Program ; Shanghai Sailing Program |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165724]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wu, Bohan; Che, Li; Minton, Timothy K. |
| 作者单位 | 1.Montana State Univ, Dept Chem & Biochem, Bozeman, MT 59717 USA 2.Dalian Maritime Univ, Coll Sci, Dalian, Liaoning, Peoples R China 3.Aerosp Res Inst Mat & Proc Technol, Beijing, Peoples R China 4.East China Univ Sci & Technol, Sch Sci, Dept Phys, Shanghai, Peoples R China 5.Beijing Inst Spacecraft Environm Engn, Beijing 100094, Peoples R China 6.Dalian Maritime Univ, Coll Environm Sci & Engn, 1 Linghai Rd, Dalian 116026, Liaoning, Peoples R China 7.Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wang, Heilong,Qian, Min,Murray, Vanessa J.,et al. Effects of hyperthermal atomic oxygen on a cyanate ester and its carbon fiber-reinforced composite[J]. HIGH PERFORMANCE POLYMERS,2019,31(4):472-482. |
| APA | Wang, Heilong.,Qian, Min.,Murray, Vanessa J..,Wu, Bohan.,Yang, Yang.,...&Minton, Timothy K..(2019).Effects of hyperthermal atomic oxygen on a cyanate ester and its carbon fiber-reinforced composite.HIGH PERFORMANCE POLYMERS,31(4),472-482. |
| MLA | Wang, Heilong,et al."Effects of hyperthermal atomic oxygen on a cyanate ester and its carbon fiber-reinforced composite".HIGH PERFORMANCE POLYMERS 31.4(2019):472-482. |
入库方式： OAI收割
来源：大连化学物理研究所
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