中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 大连化学物理研究所
  3. 中国科学院大连化学物理研究所
Crossed Molecular Beam Study of the F+D-2 (v=1, j=0) Reaction

文献类型：期刊论文

作者Huang, Long1,2; Xie, Yu-run1,2,4; Yang, Tian-gang1; Wang, Tao1,3; Dai, Dong-xu1; Xiao, Chun-lei1; Yang, Xue-ming1,3
刊名CHINESE JOURNAL OF CHEMICAL PHYSICS
出版日期2019-02-01
卷号32期号:1页码:72-76
关键词Stimulated Raman pumping D-2 vibrational excitation Molecular beam Forward scattering
ISSN号1674-0068
DOI10.1063/1674-0068/cjcp1811251
通讯作者Xiao, Chun-lei(chunleixiao@dicp.ac.cn) ; Yang, Xue-ming(xmyang@dicp.ac.cn)
英文摘要The reaction dynamics of the fluorine atom with vibrationally excited D-2 (v=1, j=0) was investigated using the crossed beam method. The scheme of stimulated Raman pumping was employed for preparation of vibrationally excited D-2 molecules. Contribution from the reaction of spin-orbit excited F*(P-2(1/2)) with vibrationally excited D-2 was not found. Reaction of spin-orbit ground F(P-2(3/2)) with vibrationally excited D-2 was measured and DF products populated in v'=2, 3, 4, 5 were observed. Compared with the vibrationally ground reaction, DF products from the vibrationally excited reaction of F(P-2(3/2))+D-2 (v=1, j=0) are rotationally "hotter". Differential cross sections at four collision energies, ranging from 0.32 kcal/mol to 2.62 kcal/mol, were obtained. Backward scattering dominates for DF products in all vibrational levels at the lowest collision energy of 0.32 kcal/mol. As the collision energy increases, angular distribution of DF products gradually shifts from backward to sideway. The collision-energy dependence of differential cross section of DF(v' =5) at forward direction was also measured. Forward-scattered signal of DF(v'=5) appears at the collision energy of 1.0 kcal/mol, and becomes dominated at 2.62 kcal/mol.
WOS关键词D-2 MOLECULES ; EXCITATION ; SECTIONS ; RESONANCES ; STRETCH ; PLUS ; CHD3
资助项目Ministry of Science and Technology[2017YFF0104500] ; Chinese Academy of Sciences ; National Natural Science Foundation of China[21573226] ; National Natural Science Foundation of China[21822305]
WOS研究方向Physics
语种英语
WOS记录号WOS:000461781200009
出版者CHINESE PHYSICAL SOC
资助机构Ministry of Science and Technology ; Ministry of Science and Technology ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology ; Ministry of Science and Technology ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology ; Ministry of Science and Technology ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Ministry of Science and Technology ; Ministry of Science and Technology ; Chinese Academy of Sciences ; Chinese Academy of Sciences ; National Natural Science Foundation of China ; National Natural Science Foundation of China
源URL[http://cas-ir.dicp.ac.cn/handle/321008/165832]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Xiao, Chun-lei; Yang, Xue-ming
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Southern Univ Sci & Technol, Sch Sci, Dept Chem, Shenzhen 518055, Peoples R China
4.Chinese Acad Sci, Shanghai Adv Res Inst, Shanghai 201210, Peoples R China
推荐引用方式
GB/T 7714		 Huang, Long,Xie, Yu-run,Yang, Tian-gang,et al. Crossed Molecular Beam Study of the F+D-2 (v=1, j=0) Reaction[J]. CHINESE JOURNAL OF CHEMICAL PHYSICS,2019,32(1):72-76.
APA Huang, Long.,Xie, Yu-run.,Yang, Tian-gang.,Wang, Tao.,Dai, Dong-xu.,...&Yang, Xue-ming.(2019).Crossed Molecular Beam Study of the F+D-2 (v=1, j=0) Reaction.CHINESE JOURNAL OF CHEMICAL PHYSICS,32(1),72-76.
MLA Huang, Long,et al."Crossed Molecular Beam Study of the F+D-2 (v=1, j=0) Reaction".CHINESE JOURNAL OF CHEMICAL PHYSICS 32.1(2019):72-76.

入库方式： OAI收割

来源：大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。