Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water
文献类型：期刊论文
| 作者 | Yin, Dulin2,3; Chen, Zengtian2,3; Li, Qingfeng2,3; Xiao, Yuxue2,3; Zhang, Chao2,3; Fu, Zaihui2,3; Liu, Yachun2,3; Yi, Xianfeng1; Zheng, Anmin1; Li, Changzhi4 |
| 刊名 | CELLULOSE
 |
| 出版日期 | 2019 |
| 卷号 | 26期号:2页码:751-762 |
| 关键词 | 5-Hydroxymethylfurfural Biochar sulfonic acid Synergistic catalysis Cellulose hydrolysis Polyamide |
| ISSN号 | 0969-0239 |
| DOI | 10.1007/s10570-018-2098-3 |
| 通讯作者 | Zhang, Chao(chaozhang2006@126.con) ; Fu, Zaihui(fzhhnnu@126.com) |
| 英文摘要 | The development of a highly efficient heterogeneous catalysis process for the hydrolysis of cellulose to reducing sugars (RSs) and especially 5-hydroxymethylfurfural (HMF) in water is highly anticipated for large-scale use of cellulosic biomass in the future. Herein, a bamboo-derived biochar sulfonic acid bearing polyamide (BCSA-PA) designed by us was found to show much higher catalytic activity, better repeatability and especially HMF yield for microwave-assisted such hydrolysis compared to the PA-free BCSA, achieving 25.60% RSs and 23.10% HMF yields with 4.71 turnover number (TON) under optimal conditions. Also, its TON value (2.58) for the conversion of cellulose into HMF was much higher than those obtained from it-catalyzed transformation of glucose (TON, 1.44) and especially fructose (TON, 0.79). The BCSA-PA showing an excellent catalysis performance in cellulose hydrolysis is likely due to the following two reasons: (1) the BCSA and especially BCSA-PA, as supported by glucose and cellobiose adsorption experiments, have a stronger affinity to -1,4-glycosidic bonds of cellulose than two monosaccharides, thereby leading to the highly-efficient hydrolysis of cellulose on the SO3H groups. (2) The acid-base synergistic catalysis between the SO3H and PA groups of BCSA-PA may be responsible for its higher HMF selectivity and excellent repeatability in water medium. The current work highlights new opportunities for the direct production of 5-HMF from glucose and especially cellulose. [GRAPHICS] . |
| WOS关键词 | LIGNOCELLULOSIC BIOMASS ; IONIC LIQUID ; BIOMIMETIC CATALYST ; SOLID ACID ; CONVERSION ; GLUCOSE ; FRUCTOSE ; TRANSFORMATION ; CHEMICALS ; BAMBOO |
| 资助项目 | National Natural Science Fund of China[21676079] ; National Natural Science Fund of China[21546010] ; National Natural Science Fund of China[20873040] ; Specialized Research Fund for the Doctoral Program of Higher Education[20124306110005] ; Natural Science Fund of Hunan Province[2018JJ3335] ; Natural Science Fund of Hunan Province[14JJ2148] ; Natural Science Fund of Hunan Province[10JJ2007] ; Innovation Platform Open Fund of Hunan College[11K044] ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province |
| WOS研究方向 | Materials Science ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000459455200007 |
| 出版者 | SPRINGER |
| 资助机构 | National Natural Science Fund of China ; National Natural Science Fund of China ; Specialized Research Fund for the Doctoral Program of Higher Education ; Specialized Research Fund for the Doctoral Program of Higher Education ; Natural Science Fund of Hunan Province ; Natural Science Fund of Hunan Province ; Innovation Platform Open Fund of Hunan College ; Innovation Platform Open Fund of Hunan College ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province ; 100 Talents Program of Hunan Province ; National Natural Science Fund of China ; National Natural Science Fund of China ; Specialized Research Fund for the Doctoral Program of Higher Education ; Specialized Research Fund for the Doctoral Program of Higher Education ; Natural Science Fund of Hunan Province ; Natural Science Fund of Hunan Province ; Innovation Platform Open Fund of Hunan College ; Innovation Platform Open Fund of Hunan College ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province ; 100 Talents Program of Hunan Province ; National Natural Science Fund of China ; National Natural Science Fund of China ; Specialized Research Fund for the Doctoral Program of Higher Education ; Specialized Research Fund for the Doctoral Program of Higher Education ; Natural Science Fund of Hunan Province ; Natural Science Fund of Hunan Province ; Innovation Platform Open Fund of Hunan College ; Innovation Platform Open Fund of Hunan College ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province ; 100 Talents Program of Hunan Province ; National Natural Science Fund of China ; National Natural Science Fund of China ; Specialized Research Fund for the Doctoral Program of Higher Education ; Specialized Research Fund for the Doctoral Program of Higher Education ; Natural Science Fund of Hunan Province ; Natural Science Fund of Hunan Province ; Innovation Platform Open Fund of Hunan College ; Innovation Platform Open Fund of Hunan College ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Collaborative Innovation Center of New Chemical Technologies for Environmental Benignity and Efficient Resource Utilization ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; Program for Science and Technology Innovative Research Team in Higher Educational Institutions of Hunan Province ; 100 Talents Program of Hunan Province ; 100 Talents Program of Hunan Province |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165938]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Chao; Fu, Zaihui |
| 作者单位 | 1.Chinese Acad Sci, Wuhan Inst Phys & Math, State Key Lab Magnet Resonance & Atom & Mol Phys, Wuhan Ctr Magnet Resonance, Wuhan 430071, Hubei, Peoples R China 2.Hunan Normal Univ, Natl & Local United Engn Lab New Petrochem Mat &, Key Lab Resource Fine Proc & Adv Mat Hunan Prov, Coll Chem & Chem Engn,Minist Educ China, Changsha 410081, Hunan, Peoples R China 3.Hunan Normal Univ, Coll Chem & Chem Engn, Minist Educ China, Key Lab Chem Biol & Tradit Chinese Med Res, Changsha 410081, Hunan, Peoples R China 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China |
| 推荐引用方式 GB/T 7714 | Yin, Dulin,Chen, Zengtian,Li, Qingfeng,et al. Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water[J]. CELLULOSE,2019,26(2):751-762. |
| APA | Yin, Dulin.,Chen, Zengtian.,Li, Qingfeng.,Xiao, Yuxue.,Zhang, Chao.,...&Li, Changzhi.(2019).Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water.CELLULOSE,26(2),751-762. |
| MLA | Yin, Dulin,et al."Acid-base synergistic catalysis of biochar sulfonic acid bearing polyamide for microwave-assisted hydrolysis of cellulose in water".CELLULOSE 26.2(2019):751-762. |
入库方式： OAI收割
来源：大连化学物理研究所
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