Rational interaction between the aimed gas and oxide surfaces enabling high-performance sensor: The case of acidic alpha-MoO3 nanorods for selective detection of triethylamine
文献类型：期刊论文
| 作者 | Feng, Liang2; He, Saihuan1; Li, Wending1; Yang, Wei1 |
| 刊名 | JOURNAL OF ALLOYS AND COMPOUNDS
 |
| 出版日期 | 2019-04-30 |
| 卷号 | 783页码:574-582 |
| 关键词 | interaction alpha-MoO3 nanorods gas sensor triethylamine impressive sensing |
| ISSN号 | 0925-8388 |
| DOI | 10.1016/j.jallcom.2018.12.349 |
| 通讯作者 | Yang, Wei(yangweight@126.com) |
| 英文摘要 | The rational interaction between the oxide surfaces and aimed gas is favorable for enhancement in gas-sensing (including rapid response and recovery rate, remarkable response value, and excellent selectivity). Herein, we have prepared acidic alpha-MoO3 nanorods through a facile hydrothermal route. The as-obtained MoO3 nanorods possess about 10 mu m in length and around 200-300 nm in diameter, respectively. The gas sensor fabricated using these MoO3 nanorods exhibits an apparent response to triethylamine (TEA) vapor with an actual detection concentration as low as 0.1 ppm at its optimal working temperature of 300 degrees C. The response time for detecting 100 ppm TEA is only 4 s, and the recovery time is less than 2 min (88 s). Moreover, the sensor shows an extremely remarkable selectivity towards TEA against other interfering gases, such as methanol, ethanol, isopropanol, acetone, toluene, and ammonia. The impressive TEA sensing of these MoO3 nanorods could be determined by suitable interaction between TEA molecules and the MoO3 surfaces (including base/acid attractive force, highly active lattice oxygen for catalytical oxidation of TEA, and fast adsorption/desorption kinetics at certain temperature). This paper provides an avenue for designing high-performance gas sensor from perspective of understanding the interaction between aimed gas and material surfaces. (C) 2018 Elsevier B.V. All rights reserved. |
| WOS关键词 | CORE-SHELL NANORODS ; SENSING PROPERTIES ; ROOM-TEMPERATURE ; HIGH-SENSITIVITY ; FAST-RESPONSE ; TRIMETHYLAMINE ; NANOSHEETS ; MOLYBDENUM ; CONSTRUCTION ; GROWTH |
| 资助项目 | National Natural Science Foundation of China[61603279] ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Wuhan Institute of Technology |
| WOS研究方向 | Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000458872600067 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Wuhan Institute of Technology ; Wuhan Institute of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Wuhan Institute of Technology ; Wuhan Institute of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Wuhan Institute of Technology ; Wuhan Institute of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Open Foundation from CAS Key Lab of Separation Sciences for Analytical Chemistry, Dalian Institute of Chemical Physics, Chinese Academy of Sciences (CAS) ; Wuhan Institute of Technology ; Wuhan Institute of Technology |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165944]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yang, Wei |
| 作者单位 | 1.Wuhan Inst Technol, Sch Chem & Environm Engn, Minist Educ, Key Lab Green Chem Proc, Wuhan 430205, Hubei, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Key Lab Separat Sci Analyt Chem, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Feng, Liang,He, Saihuan,Li, Wending,et al. Rational interaction between the aimed gas and oxide surfaces enabling high-performance sensor: The case of acidic alpha-MoO3 nanorods for selective detection of triethylamine[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2019,783:574-582. |
| APA | Feng, Liang,He, Saihuan,Li, Wending,&Yang, Wei.(2019).Rational interaction between the aimed gas and oxide surfaces enabling high-performance sensor: The case of acidic alpha-MoO3 nanorods for selective detection of triethylamine.JOURNAL OF ALLOYS AND COMPOUNDS,783,574-582. |
| MLA | Feng, Liang,et al."Rational interaction between the aimed gas and oxide surfaces enabling high-performance sensor: The case of acidic alpha-MoO3 nanorods for selective detection of triethylamine".JOURNAL OF ALLOYS AND COMPOUNDS 783(2019):574-582. |
入库方式： OAI收割
来源：大连化学物理研究所
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