Breaking Long-Range Order in Iridium Oxide by Alkali Ion for Efficient Water Oxidation
文献类型：期刊论文
| 作者 | Xiao, Hai2; Huang, Yanqiang4; Liu, Bin1; Gao, Jiajian1; Xu, Cong-Qjao2; Hung, Sung-Fu3; Liu, Wei4; Cai, Weizheng1; Zeng, Zhiping1; Jia, Chunmiao1 |
| 刊名 | JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
 |
| 出版日期 | 2019-02-20 |
| 卷号 | 141期号:7页码:3014-3023 |
| ISSN号 | 0002-7863 |
| DOI | 10.1021/jacs.8b11456 |
| 通讯作者 | Li, Jun(junli@tsinghua.edu.cn) ; Huang, Yanqiang(yqhuang@dicp.ac.cn) ; Liu, Bin(liubin@ntu.edu.sg) |
| 英文摘要 | Oxygen electrochemistry plays a critical role in clean energy technologies such as fuel cells and electrolyzers, but the oxygen evolution reaction (OER) severely restricts the efficiency of these devices due to its slow kinetics. Here, we show that via incorporation of lithium ion into iridium oxide, the thus obtained amorphous iridium oxide (Li-IrOx) demonstrates outstanding water oxidation activity with an OER current density of 10 mA/cm(2) at 270 mV overpotential for 10 h of continuous operation in acidic electrolyte. DFT calculations show that lithium incorporation into iridium oxide is able to lower the activation barrier for OER X-ray absorption characterizations indicate that both amorphous Li-IrOx and rutile IrO2 own similar [IrO6] octahedron units but have different [IrO6] octahedron connection modes. Oxidation of iridium to higher oxidation states along with shrinkage in the Ir-O bond was observed by in situ X-ray absorption spectroscopy on amorphous Li-IrOx, but not on rutile IrO2 under OER operando conditions. The much more "flexible" disordered [IrO6] octahedrons with higher oxidation states in amorphous Li-IrOx as compared to the periodically interconnected "rigid" [IrO6] octahedrons in crystalline IrO2 are able to act as more electrophilic centers and thus effectively promote the fast turnover of water oxidation. |
| WOS关键词 | OXYGEN EVOLUTION REACTION ; TOTAL-ENERGY CALCULATIONS ; ELECTRONIC-STRUCTURE ; TAFEL LINES ; IRO2 ; ELECTROCATALYSTS ; MECHANISM ; KINETICS ; NANOPARTICLES ; CATALYSTS |
| 资助项目 | Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1[RG10/16] ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1[RG111/15] ; National Key R&D Program of China[2016YFA0202804] ; National Natural Science Foundation of China[21590792] ; National Natural Science Foundation of China[91645203] ; National Natural Science Foundation of China[21521091] ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2[MOE2016-T2-2-004] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000459642000035 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1 ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1 ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1 ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 1 ; National Key R&D Program of China ; National Key R&D Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2 ; Singapore Ministry of Education Academic Research Fund (AcRF) Tier 2 |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/165998]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Huang, Yanqiang; Liu, Bin; Li, Jun |
| 作者单位 | 1.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore 2.Tsinghua Univ, Dept Chem, Beijing 100084, Peoples R China 3.Natl Taiwan Univ, Dept Chem, Taipei 106, Taiwan 4.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China 5.Southern Univ Sci & Technol, Dept Chem, Shenzhen 518055, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xiao, Hai,Huang, Yanqiang,Liu, Bin,et al. Breaking Long-Range Order in Iridium Oxide by Alkali Ion for Efficient Water Oxidation[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,2019,141(7):3014-3023. |
| APA | Xiao, Hai.,Huang, Yanqiang.,Liu, Bin.,Gao, Jiajian.,Xu, Cong-Qjao.,...&Li, Jun.(2019).Breaking Long-Range Order in Iridium Oxide by Alkali Ion for Efficient Water Oxidation.JOURNAL OF THE AMERICAN CHEMICAL SOCIETY,141(7),3014-3023. |
| MLA | Xiao, Hai,et al."Breaking Long-Range Order in Iridium Oxide by Alkali Ion for Efficient Water Oxidation".JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 141.7(2019):3014-3023. |
入库方式： OAI收割
来源：大连化学物理研究所
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