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Na3V2(PO4)(3): an advanced cathode for sodium-ion batteries

文献类型：期刊论文

作者Tan, Huiteng1; Yang, Dan1; Huang, Shaoming1; Yu, Yan2,4; Zhang, Xianghua1; Rui, Xianhong1,2,3; Chen, Dong1
刊名NANOSCALE
出版日期2019-02-14
卷号11期号:6页码:2556-2576
ISSN号2040-3364
DOI10.1039/c8nr09391a
通讯作者Rui, Xianhong(xhrui@gdut.edu.cn) ; Huang, Shaoming(smhuang@gdut.edu.cn) ; Yu, Yan(yanyumse@ustc.edu.cn)
英文摘要Sodium-ion batteries (SIBs) are considered to be the most promising electrochemical energy storage devices for large-scale grid and electric vehicle applications due to the advantages of resource abundance and cost-effectiveness. The electrochemical performance of SIBs largely relies on the intrinsic chemical properties of the cathodic materials. Among the various cathodes, rhombohedral Na3V2(PO4)(3) (NVP), a typical sodium super ionic conductor (NASICON) compound, is very popular owing to its high Na+ mobility and firm structural stability. However, the relatively low electronic conductivity makes the theoretical capacity of NVP cathodes unviable even at low rates, not to mention the high rate of charging/discharging. This is a major drawback of NVPs, limiting their future large-scale applications. Herein, a comprehensive review of the recent progresses made in NVP fabrication has been presented, mainly including the strategies of developing NVP/carbon hybrid materials and elemental doping to improve the electronic conductivity of NVP cathodes and designing 3D porous architectures to enhance Na-ion transportation. Moreover, the application of NVP cathodic materials in Na-ion full batteries is summarized, too. Finally, some remarks are made on the challenges and perspectives for the future development of NVP cathodes.
WOS关键词CARBON-COATED NA3V2(PO4)(3) ; HIGH-PERFORMANCE ANODE ; ENHANCED ELECTROCHEMICAL PERFORMANCE ; SUPERIOR RATE CAPABILITY ; NASICON STRUCTURED NA3V2(PO4)(3) ; EXCELLENT CYCLING STABILITY ; NA-STORAGE CATHODE ; HARD-CARBON ; LITHIUM-ION ; LONG-LIFE
资助项目National Key R&D Research Program of China[2018YFB0905400] ; National Natural Science Foundation of China[51622210] ; National Natural Science Foundation of China[51872277] ; National Natural Science Foundation of China[21606003] ; National Natural Science Foundation of China[51802044] ; National Natural Science Foundation of China[51420105002] ; DNL cooperation Fund, CAS[DNL180310] ; Fundamental Research Funds for the Central Universities[WK3430000004] ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
WOS记录号WOS:000459579400001
出版者ROYAL SOC CHEMISTRY
资助机构National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization ; National Key R&D Research Program of China ; National Key R&D Research Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; DNL cooperation Fund, CAS ; DNL cooperation Fund, CAS ; Fundamental Research Funds for the Central Universities ; Fundamental Research Funds for the Central Universities ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; Opening Projects of CAS Key Laboratory of Materials for Energy Conversion ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization ; State Key Laboratory of Vanadium and Titanium Resources Comprehensive Utilization
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166002]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Huang, Shaoming; Yu, Yan; Rui, Xianhong
作者单位1.Guangdong Univ Technol, Guangzhou Key Lab Low Dimens Mat & Energy Storage, Collaborat Innovat Ctr Adv Energy Mat, Sch Mat & Energy, Guangzhou 510006, Guangdong, Peoples R China
2.Univ Sci & Technol China, Chinese Acad Sci, Dept Mat Sci & Engn, Key Lab Mat Energy Convers, Hefei 230026, Anhui, Peoples R China
3.State Key Lab Vanadium & Titanium Resources, Comprehens Utilizat, Panzhihua 617000, Peoples R China
4.Chinese Acad Sci, Dalian Natl Lab Clean Energy DNL, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714		 Tan, Huiteng,Yang, Dan,Huang, Shaoming,et al. Na3V2(PO4)(3): an advanced cathode for sodium-ion batteries[J]. NANOSCALE,2019,11(6):2556-2576.
APA Tan, Huiteng.,Yang, Dan.,Huang, Shaoming.,Yu, Yan.,Zhang, Xianghua.,...&Chen, Dong.(2019).Na3V2(PO4)(3): an advanced cathode for sodium-ion batteries.NANOSCALE,11(6),2556-2576.
MLA Tan, Huiteng,et al."Na3V2(PO4)(3): an advanced cathode for sodium-ion batteries".NANOSCALE 11.6(2019):2556-2576.

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来源：大连化学物理研究所

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