中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Toward Fundamentals of Confined Electrocatalysis in Nanoscale Reactors

文献类型:期刊论文

作者Xiao, Jianping1,2; Li, Haobo1; Guo, Chenxi1; Fu, Qiang2
刊名JOURNAL OF PHYSICAL CHEMISTRY LETTERS
出版日期2019-02-07
卷号10期号:3页码:533-539
ISSN号1948-7185
DOI10.1021/acs.jpclett.8b03448
通讯作者Xiao, Jianping(xiao@dicp.ac.cn)
英文摘要A number of experiments have demonstrated that electrochemical reactions are feasible in confined nanoscale reactors, while what the fundamentals of confined electrochemistry are is not clear. Using first-principles calculations and electrochemical modeling, we find that the capacitance in the confined nanoscale reactors can be significantly enhanced, compared to an open electrode interface, essentially promoting the electrochemical reactions and charge transfer efficiency in nanoscale reactors. More importantly, this is a general character, as found in a variety of electrochemical and thermochemical reactions. At the end, we use the recently defined new concept of "confinement energy" for understanding the nature of confined electrochemistry from both thermochemical and electrochemical points of view.
WOS关键词GRAPHENE FILMS ; CATALYSIS ; POINTS ; SIZE
资助项目National Science Foundation of China[21802124] ; National Science Foundation of China[91845103] ; Ministry of Science and Technology of China[2016YFA0200200] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020000]
WOS研究方向Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics
语种英语
出版者AMER CHEMICAL SOC
WOS记录号WOS:000458704800035
资助机构National Science Foundation of China ; National Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Science Foundation of China ; National Science Foundation of China ; Ministry of Science and Technology of China ; Ministry of Science and Technology of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166044]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Xiao, Jianping
作者单位1.Westlake Univ, Sch Sci, Westlake Inst Adv Study, Inst Nat Sci, Hangzhou 310024, Zhejiang, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Zhongshan Rd 457, Dalian 116023, Peoples R China
推荐引用方式
GB/T 7714
Xiao, Jianping,Li, Haobo,Guo, Chenxi,et al. Toward Fundamentals of Confined Electrocatalysis in Nanoscale Reactors[J]. JOURNAL OF PHYSICAL CHEMISTRY LETTERS,2019,10(3):533-539.
APA Xiao, Jianping,Li, Haobo,Guo, Chenxi,&Fu, Qiang.(2019).Toward Fundamentals of Confined Electrocatalysis in Nanoscale Reactors.JOURNAL OF PHYSICAL CHEMISTRY LETTERS,10(3),533-539.
MLA Xiao, Jianping,et al."Toward Fundamentals of Confined Electrocatalysis in Nanoscale Reactors".JOURNAL OF PHYSICAL CHEMISTRY LETTERS 10.3(2019):533-539.

入库方式: OAI收割

来源:大连化学物理研究所

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