中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
Effect of coke formation on catalytic activity tests for catalytic combustion of toluene: the difficulty of measuring TOF and T-98 accurately

文献类型:期刊论文

作者Yu, Qinqin2; Wang, Hui1; Tian, Penghui1; Chen, Zewen1; Wu, Shengji1; Yang, Wei1; Zhou, Jie1
刊名CHEMICAL ENGINEERING COMMUNICATIONS
出版日期2019
卷号206期号:1页码:22-32
ISSN号0098-6445
关键词Catalytic combustion Coke formation Doped catalysts TOF Toluene Volatile organic compounds (VOCs)
DOI10.1080/00986445.2018.1470510
通讯作者Wu, Shengji(wushengji26@hdu.edu.cn) ; Yu, Qinqin(ruby80@163.com)
英文摘要Catalytic combustion is considered as one of the most efficient routes for removing volatile organic compounds. In recent years, the catalytic activities of catalysts have usually been evaluated by the values of TOF and T-98. It is difficult, however, to measure the values accurately because the influencing factors are numerous and easy to be overlooked. In this work, the influence of the catalytic test procedure on TOF and T-98 values was investigated. Supported Pd or Pt catalysts were prepared via the incipient wetness impregnation method. The catalytic activities of the same catalyst were very different when evaluated in different catalytic test procedures. Indeed, the catalytic test procedures affected the TOF and T-98 values remarkably. It was found that the different coking behavior in different catalytic test procedures is the major cause. The influences on coke formation in toluene combustion - such as reaction temperature, reaction time, and catalyst type - were investigated.
WOS关键词VOLATILE ORGANIC-COMPOUNDS ; TOTAL OXIDATION ; STRUCTURAL-CHANGES ; SUPPORTED COBALT ; ZSM-5 ; GOLD ; CHLOROBENZENE ; PERFORMANCE ; PALLADIUM ; ZEOLITES
资助项目Zhejiang Province Nature Science Foundation of China[LQ17B060006]
WOS研究方向Engineering
语种英语
出版者TAYLOR & FRANCIS INC
WOS记录号WOS:000459659300003
资助机构Zhejiang Province Nature Science Foundation of China ; Zhejiang Province Nature Science Foundation of China ; Zhejiang Province Nature Science Foundation of China ; Zhejiang Province Nature Science Foundation of China ; Zhejiang Province Nature Science Foundation of China ; Zhejiang Province Nature Science Foundation of China ; Zhejiang Province Nature Science Foundation of China ; Zhejiang Province Nature Science Foundation of China
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166050]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Yu, Qinqin; Wu, Shengji
作者单位1.Hangzhou Dianzi Univ, Coll Mech Engn, Dept Environm Sci & Technol, Xiasha Univ Pk, Hangzhou, Zhejiang, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian, Peoples R China
推荐引用方式
GB/T 7714
Yu, Qinqin,Wang, Hui,Tian, Penghui,et al. Effect of coke formation on catalytic activity tests for catalytic combustion of toluene: the difficulty of measuring TOF and T-98 accurately[J]. CHEMICAL ENGINEERING COMMUNICATIONS,2019,206(1):22-32.
APA Yu, Qinqin.,Wang, Hui.,Tian, Penghui.,Chen, Zewen.,Wu, Shengji.,...&Zhou, Jie.(2019).Effect of coke formation on catalytic activity tests for catalytic combustion of toluene: the difficulty of measuring TOF and T-98 accurately.CHEMICAL ENGINEERING COMMUNICATIONS,206(1),22-32.
MLA Yu, Qinqin,et al."Effect of coke formation on catalytic activity tests for catalytic combustion of toluene: the difficulty of measuring TOF and T-98 accurately".CHEMICAL ENGINEERING COMMUNICATIONS 206.1(2019):22-32.

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来源:大连化学物理研究所

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