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Dual-phase membrane reactor for hydrogen separation with high tolerance to CO2 and H2S impurities

文献类型：期刊论文

作者Li, Hongbo1; Cai, Lili1,2; Yang, Weishen1; Hu, Shiqing1,2; Cao, Zhongwei1; Zhu, Xuefeng1
刊名AICHE JOURNAL
出版日期2019-03-01
卷号65期号:3页码:1088-1096
ISSN号0001-1541
关键词hydrogen separation oxygen-permeable membranes membrane reactor conductivity CO2 and H2S impurities
DOI10.1002/aic.16491
通讯作者Zhu, Xuefeng(zhuxf@dicp.ac.cn) ; Yang, Weishen(yangws@dicp.ac.cn)
英文摘要Catalytic membrane reactors based on oxygen-permeable membranes are recently studied for hydrogen separation because their hydrogen separation rates and separation factors are comparable to those of Pd-based membranes. New membrane materials with high performance and good tolerance to CO2 and H2S impurities are highly desired. In this work, a new membrane material Ce0.85Sm0.15O1.925-Sr2Fe1.5Mo0.5O6-delta (SDC-SFM) was prepared for hydrogen separation. It exhibits high conductivities at low oxygen partial pressures, which is benefit to electron transfer and ion diffusion. A high hydrogen separation rate of 6.6 mL cm(-2) min(-1) was obtained on a 0.5-mm-thick membrane coated with Ni/SDC catalyst at 900 degrees C. The membrane reactor was operated steadily for 532 h under atmospheres containing CO2 and H2S impurities. Various characterizations reveal that SDC-SFM has good stability in the membrane reactor for hydrogen separation. All facts confirm that SDC-SFM is promising for hydrogen separation in practical applications. (c) 2018 American Institute of Chemical Engineers
WOS关键词HOLLOW-FIBER MEMBRANE ; OXYGEN PERMEATION ; PARTIAL OXIDATION ; FUEL-CELL ; COMPOSITE ; ELECTROCATALYSTS ; METHANE ; DESIGN ; SYNGAS ; SYSTEM
资助项目National Natural Science Foundation of China[91545202] ; National Natural Science Foundation of China[21776267] ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS)[XDB17000000] ; project of Dalian Outstanding Young Scientific and Technical Talents[2016RJ07] ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DICPQIBEBT[UN201708] ; DICP[DMTO201503]
WOS研究方向Engineering
语种英语
出版者WILEY
WOS记录号WOS:000457747600020
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DICPQIBEBT ; DICPQIBEBT ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DICPQIBEBT ; DICPQIBEBT ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DICPQIBEBT ; DICPQIBEBT ; DICP ; DICP ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; Strategic Priority Research Program of the Chinese Academy of Sciences (CAS) ; project of Dalian Outstanding Young Scientific and Technical Talents ; project of Dalian Outstanding Young Scientific and Technical Talents ; Dalian National Laboratory for Clean Energy (DNL), CAS ; Dalian National Laboratory for Clean Energy (DNL), CAS ; DICPQIBEBT ; DICPQIBEBT ; DICP ; DICP
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166062]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Yang, Weishen; Zhu, Xuefeng
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Li, Hongbo,Cai, Lili,Yang, Weishen,et al. Dual-phase membrane reactor for hydrogen separation with high tolerance to CO2 and H2S impurities[J]. AICHE JOURNAL,2019,65(3):1088-1096.
APA Li, Hongbo,Cai, Lili,Yang, Weishen,Hu, Shiqing,Cao, Zhongwei,&Zhu, Xuefeng.(2019).Dual-phase membrane reactor for hydrogen separation with high tolerance to CO2 and H2S impurities.AICHE JOURNAL,65(3),1088-1096.
MLA Li, Hongbo,et al."Dual-phase membrane reactor for hydrogen separation with high tolerance to CO2 and H2S impurities".AICHE JOURNAL 65.3(2019):1088-1096.

入库方式： OAI收割

来源：大连化学物理研究所

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