Synthesis, Characterization and Luminescent Properties of Two Copper(I) Complexes Based on 2,2 '-Biquinoline and Phosphorous Ligand
文献类型：期刊论文
| 作者 | Jin Qiong-Hua2; Wang Yu2; Lin Sen2; Liu Jian-Ming1; Li Zhong-Feng2; Zhang Jiang-Wei3; Sun Ling-Zhi2 |
| 刊名 | CHINESE JOURNAL OF STRUCTURAL CHEMISTRY
 |
| 出版日期 | 2018-08-15 |
| 卷号 | 37期号:8页码:1313-1322 |
| 关键词 | copper crystal structures 2,2 '-biquinoline luminescence |
| ISSN号 | 0254-5861 |
| DOI | 10.14102/j.cnki.0254-5861.2011-1942 |
| 通讯作者 | Jin Qiong-Hua(jinqh@cnu.edu.cn) |
| 英文摘要 | Three new copper(I) complexes, namely [Cu(DPEphos)(Biq)]CF3SO3 (1) and [Cu(PPh3)(2)(Biq)]CF3SO3 (2) and [Cu(PPh3)(2)(Biq)]ClO4(3) (DPEphos = bis [2-(diphenylphosp hino)phenyl]ether, PPh3 = triphenylphosphine and Biq = 2,2'-biquinoline), are synthesized and characterized by IR, H-1 NMR, P-31 NMR, fluorescence spectra and terahertz time-domain spectroscopy (THz-TDS). Complex 1 crystallizes in triclinic, space group P (1) over bar with a = 12.6997(5), b = 13.2813(5), c = 15.3593(6) angstrom, alpha = 80.211(3)degrees, beta= 88.752(3)degrees, gamma = 70.113(3)degrees, V = 2398.85(15) angstrom(3), C55H41.2CUF3N2O2,M-r = 1018.27, Z = 2, D-c = 1.410 g/cm(3), F(000) = 1048, mu = 0.628 mm(-1), the final R = 0.0450 and wR = 0.1105 for 9419 observed reflections (I > 2 sigma(I)). Complex 2 crystallizes in monoclinic, space group C2/c with a = 19.9961(7), b = 15.9774(5), c = 17.7908(6) angstrom, beta = 119.758(4)degrees, V = 4982.8(3) angstrom(3), C56.47H47.88CuF3N2O4.47P2S, Mr = 1040.54, Z = 4, D-c = 1.387 g/cm(3), F(000) = 2154, mu = 0.606 mm(-1), the final R = 0.0430 and wR = 0.1218 for 4897 observed reflections (I > 2 sigma(I)). Complex 3 crystallizes in monoclinic, space group C2/c with a = 19.7534(8), b = 15.0797(5), c = 17.8097(7) angstrom, beta = 116.400(5)degrees, V = 4751.8(3) angstrom(3), C-56 H(45)C1CuN(3)O(4)P(2), M-r= 984.88, Z = 4, D-c= 1.377 g/cm(3), F(000) = 2040, mu = 0.635 mm(-1), the final R = 0.0731 and wR = 0.2180 for 4670 observed reflections (I > 2 sigma(I)). In the emission spectra, shifts of emission peak are derived from ligand-centered (pi-pi*) transition. |
| WOS关键词 | STRUCTURAL-CHARACTERIZATION ; SILVER(I) COMPLEXES ; SERIES ; ANION |
| 资助项目 | National Natural Science Foundation of China[21171119] ; National Natural Science Foundation of China[81573822] ; Beijing Municipal Natural Science Foundation[2172017] |
| WOS研究方向 | Chemistry ; Crystallography |
| 语种 | 英语 |
| WOS记录号 | WOS:000454083000015 |
| 出版者 | CHINESE JOURNAL STRUCTURAL CHEMISTRY |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Beijing Municipal Natural Science Foundation ; Beijing Municipal Natural Science Foundation |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166338]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Jin Qiong-Hua |
| 作者单位 | 1.Peking Univ, Sch Math Sci, Beijing 100871, Peoples R China 2.Capital Normal Univ, Dept Chem, Beijing 100048, Peoples R China 3.Chinese Acad Sci, Gold Catalysis Res Ctr, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jin Qiong-Hua,Wang Yu,Lin Sen,et al. Synthesis, Characterization and Luminescent Properties of Two Copper(I) Complexes Based on 2,2 '-Biquinoline and Phosphorous Ligand[J]. CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,2018,37(8):1313-1322. |
| APA | Jin Qiong-Hua.,Wang Yu.,Lin Sen.,Liu Jian-Ming.,Li Zhong-Feng.,...&Sun Ling-Zhi.(2018).Synthesis, Characterization and Luminescent Properties of Two Copper(I) Complexes Based on 2,2 '-Biquinoline and Phosphorous Ligand.CHINESE JOURNAL OF STRUCTURAL CHEMISTRY,37(8),1313-1322. |
| MLA | Jin Qiong-Hua,et al."Synthesis, Characterization and Luminescent Properties of Two Copper(I) Complexes Based on 2,2 '-Biquinoline and Phosphorous Ligand".CHINESE JOURNAL OF STRUCTURAL CHEMISTRY 37.8(2018):1313-1322. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。