中国科学院机构知识库网格
Chinese Academy of Sciences Institutional Repositories Grid
首页 机构 成果 学者
  
  1. CAS IR Grid
  2. 大连化学物理研究所
  3. 中国科学院大连化学物理研究所
Single-atom catalyst: a rising star for green synthesis of fine chemicals

文献类型：期刊论文

作者Liu, Wengang1,2; Zhang, Tao1; Zhang, Leilei1; Ren, Yujing1,2; Wang, Aiqin1
刊名NATIONAL SCIENCE REVIEW
出版日期2018-09-01
卷号5期号:5页码:653-672
关键词single-atom catalysts fine chemicals green synthesis structure-reactivity relationship heterogeneous catalysis
ISSN号2095-5138
DOI10.1093/nsr/nwy077
通讯作者Wang, Aiqin(aqwang@dicp.ac.cn) ; Zhang, Tao(taozhang@dicp.ac.cn)
英文摘要The green synthesis of fine chemicals calls for a new generation of efficient and robust catalysts. Single-atom catalysts (SACs), in which all metal species are atomically dispersed on a solid support, and which often consist of well-defined mononuclear active sites, are expected to bridge homogeneous and heterogeneous catalysts for liquid-phase organic transformations. This review summarizes major advances in the SAC-catalysed green synthesis of fine chemicals in the past several years, with a focus on the catalytic activity, selectivity and reusability of SACs in various organic reactions. The relationship between catalytic performance and the active site structure is discussed in terms of the valence state, coordination environment and anchoring chemistry of single atoms to the support, in an effort to guide the rational design of SACs in this special area, which has traditionally been dominated by homogeneous catalysis. Finally, the challenges remaining in this research area are discussed and possible future research directions are proposed.
WOS关键词N-C CATALYST ; SELECTIVE AEROBIC OXIDATION ; FIXED-BED HYDROFORMYLATION ; FRUSTRATED LEWIS PAIRS ; CHEMOSELECTIVE HYDROGENATION ; FUNCTIONALIZED NITROARENES ; LEVULINIC ACID ; ETHYLENE-GLYCOL ; EFFICIENT ; REDUCTION
资助项目National Natural Science Foundation of China[21373206] ; National Natural Science Foundation of China[21690080] ; National Natural Science Foundation of China[21690084] ; National Natural Science Foundation of China[21503219] ; National Natural Science Foundation of China[21673228] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDB17020100] ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801]
WOS研究方向Science & Technology - Other Topics
语种英语
WOS记录号WOS:000448667000016
出版者OXFORD UNIV PRESS
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; National Key Projects for Fundamental Research and Development of China ; National Key Projects for Fundamental Research and Development of China
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166422]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Zhang, Tao; Wang, Aiqin
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Wengang,Zhang, Tao,Zhang, Leilei,et al. Single-atom catalyst: a rising star for green synthesis of fine chemicals[J]. NATIONAL SCIENCE REVIEW,2018,5(5):653-672.
APA Liu, Wengang,Zhang, Tao,Zhang, Leilei,Ren, Yujing,&Wang, Aiqin.(2018).Single-atom catalyst: a rising star for green synthesis of fine chemicals.NATIONAL SCIENCE REVIEW,5(5),653-672.
MLA Liu, Wengang,et al."Single-atom catalyst: a rising star for green synthesis of fine chemicals".NATIONAL SCIENCE REVIEW 5.5(2018):653-672.

入库方式： OAI收割

来源：大连化学物理研究所

浏览0
下载0
收藏0
其他版本

除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。