Isolation and Characterization of Four Phosphorus Cluster Anions P-7(3-), P-14(4-), P-16(2-) and P-26(4-) from the Nucleophilic Functionalization of White Phosphorus with 1,4-Dilithio-1,3-butadienes
文献类型：期刊论文
| 作者 | Hu, Jingyuan; Zhang, Wen-Xiong; Xi, Zhenfeng; Du, Shanshan; Chai, Zhengqi |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2019 |
| 卷号 | 37期号:1页码:71-75 |
| ISSN号 | 1001-604X |
| 关键词 | organolithium phosphorus clusters P4 functionalization phospholyl lithium white phosphorus |
| DOI | 10.1002/cjoc.201800482 |
| 通讯作者 | Zhang, Wen-Xiong(wx_zhang@pku.edu.cn) |
| 英文摘要 | .Summary of main observation and conclusion Studies on the aggregation degrees of negatively charged phosphides derived from the nucleophilic P-4 functionalization could help understand the pathway of phosphorus atoms degradation or aggregation. In this report, we have isolated and characterized four phosphorus cluster anions (P-7(3-), P-14(4-), P-16(2-), and P-26(4-)) from the nucleophilic functionalization of P-4 with 1,4-dilithio-1,3-butadienes. These phosphorus clusters could be rationalized as the P-atom-containing products besides the main phospholyl lithium. Their structural features and P-31 NMR behaviors are discussed based on single crystal X-ray diffraction analysis and P-31{H-1} COSY NMR analysis. |
| WOS关键词 | P-4 ACTIVATION ; ELEMENTAL PHOSPHORUS ; CRYSTAL-STRUCTURES ; REACTIVITY ; CHEMISTRY ; POLYPHOSPHIDES ; COMPLEX ; BOND ; PHOSPHIDES ; LIGAND |
| 资助项目 | National Science Fund for Distinguished Young Scholars of China[21725201] ; National Natural Science Foundation of China[21572005] ; National Natural Science Foundation of China[21890721] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| WOS记录号 | WOS:000453403000012 |
| 资助机构 | National Science Fund for Distinguished Young Scholars of China ; National Science Fund for Distinguished Young Scholars of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Science Fund for Distinguished Young Scholars of China ; National Science Fund for Distinguished Young Scholars of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Science Fund for Distinguished Young Scholars of China ; National Science Fund for Distinguished Young Scholars of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Science Fund for Distinguished Young Scholars of China ; National Science Fund for Distinguished Young Scholars of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166424]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Wen-Xiong |
| 作者单位 | Peking Univ, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Hu, Jingyuan,Zhang, Wen-Xiong,Xi, Zhenfeng,et al. Isolation and Characterization of Four Phosphorus Cluster Anions P-7(3-), P-14(4-), P-16(2-) and P-26(4-) from the Nucleophilic Functionalization of White Phosphorus with 1,4-Dilithio-1,3-butadienes[J]. CHINESE JOURNAL OF CHEMISTRY,2019,37(1):71-75. |
| APA | Hu, Jingyuan,Zhang, Wen-Xiong,Xi, Zhenfeng,Du, Shanshan,&Chai, Zhengqi.(2019).Isolation and Characterization of Four Phosphorus Cluster Anions P-7(3-), P-14(4-), P-16(2-) and P-26(4-) from the Nucleophilic Functionalization of White Phosphorus with 1,4-Dilithio-1,3-butadienes.CHINESE JOURNAL OF CHEMISTRY,37(1),71-75. |
| MLA | Hu, Jingyuan,et al."Isolation and Characterization of Four Phosphorus Cluster Anions P-7(3-), P-14(4-), P-16(2-) and P-26(4-) from the Nucleophilic Functionalization of White Phosphorus with 1,4-Dilithio-1,3-butadienes".CHINESE JOURNAL OF CHEMISTRY 37.1(2019):71-75. |
入库方式： OAI收割
来源：大连化学物理研究所
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