A hydrated amorphous iron oxide nanoparticle as active water oxidation catalyst
文献类型：期刊论文
| 作者 | Huang, Qinge; Huang, Baokun; Li, Can; Zhang, Fuxiang; Chen, Zheng |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2019 |
| 卷号 | 40期号:1页码:38-42 |
| 关键词 | Artificial photosynthesis Water oxidation Iron oxide Hydration Amorphous |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(18)63190-0 |
| 通讯作者 | Zhang, Fuxiang(fxzhang@dicp.ac.cn) ; Li, Can(canli@dicp.ac.cn) |
| 英文摘要 | Developing efficient water oxidation catalysts (WOCs) with earth-abundant elements still remains a challenging task for artificial photosynthesis. Iron-based WOC is a promising candidate because it is economically cheap, little toxic and environmentally friendly. In this study, we found that the catalytic water oxidation activity on amorphous iron-based oxide/hydroxide (FeOx) can be decreased by an order of magnitude after the dehydration process at room temperature. Thermogravimetric analysis, XRD and Raman results indicated that the dehydration process of FeOx at room temperature causes the almost completely loss of water molecule with no bulk structural changes. Based on this finding, we prepared hydrated ultrasmall (ca. 2.2 nm) FeOx nanoparticles of amorphous feature, which turns out to be extremely active as WOC with turnover frequency (TOF) up to 9.3 s(-1) in the photocatalytic Ru(bpy)3(2+)-Na2S2O8 system. Our findings suggest that future design of active iron-based oxides as WOCs requires the consideration of their hydration status. (C) 2019, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | OXYGEN EVOLUTION ; HETEROGENEOUS CATALYSTS ; ELECTROCATALYSIS ; PHOTOCATALYSIS ; FEOOH |
| 资助项目 | Basic Research Program of China (973 Program)[2014CB239403] ; National Natural Science Foundation of China[21522306] ; National Natural Science Foundation of China[21633009] ; Key Research Program of Frontier Sciences, CAS[QYZDY-SSW-JSC023] |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000453646500005 |
| 出版者 | SCIENCE PRESS |
| 资助机构 | Basic Research Program of China (973 Program) ; Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Basic Research Program of China (973 Program) ; Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Basic Research Program of China (973 Program) ; Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS ; Basic Research Program of China (973 Program) ; Basic Research Program of China (973 Program) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Key Research Program of Frontier Sciences, CAS ; Key Research Program of Frontier Sciences, CAS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166440]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Can; Zhang, Fuxiang |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Huang, Qinge,Huang, Baokun,Li, Can,et al. A hydrated amorphous iron oxide nanoparticle as active water oxidation catalyst[J]. CHINESE JOURNAL OF CATALYSIS,2019,40(1):38-42. |
| APA | Huang, Qinge,Huang, Baokun,Li, Can,Zhang, Fuxiang,&Chen, Zheng.(2019).A hydrated amorphous iron oxide nanoparticle as active water oxidation catalyst.CHINESE JOURNAL OF CATALYSIS,40(1),38-42. |
| MLA | Huang, Qinge,et al."A hydrated amorphous iron oxide nanoparticle as active water oxidation catalyst".CHINESE JOURNAL OF CATALYSIS 40.1(2019):38-42. |
入库方式： OAI收割
来源：大连化学物理研究所
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