Gold Cluster-CeO2 Nanostructured Hybrid Architectures as Catalysts for Selective Oxidation of Inert Hydrocarbons
文献类型：期刊论文
| 作者 | Dai, Sheng1; Liu, Yali2; Zhang, Pengfei1; Liu, Junmin2; Wang, Tao2; Huo, Qisheng2; Yang, Li3; Sun, Lei3; Qiao, Zhen-An2 |
| 刊名 | CHEMISTRY OF MATERIALS
 |
| 出版日期 | 2018-12-11 |
| 卷号 | 30期号:23页码:8579-8586 |
| ISSN号 | 0897-4756 |
| DOI | 10.1021/acs.chemmater.8b03624 |
| 通讯作者 | Sun, Lei(slei@dicp.ac.cn) ; Qiao, Zhen-An(qiaozhenan@jlu.edu.cn) ; Dai, Sheng(dais@ornl.gov) |
| 英文摘要 | Gold clusters with ultrasmall size and special structure are highly attractive for heterogeneous catalysis. However, stabilizing gold clusters under thermal treatment remains a major hurdle on the way toward real-world application. Herein, we report an effective approach that stabilizing gold clusters (Au-25 and Au-144) within mesoporous ceria nanospheres via a two phase overcoating process. High-esolution aberration-corrected STEM studies indicated that gold clusters were encapsulated and confined in the intersectional channels of ceria, and the encapsulated clusters were demonstrated to be resistant to sintering under high-emperature thermal treatment. The solvent-free aerobic oxidation of toluene and ethylbenzene was carried out to illustrate the performance of gold clusters in catalysis, and these materials showed excellent catalytic activities and afforded much higher turnover frequencies (up to 5634 and 55 027 turnovers for toluene and ethylbenzene oxidation), which are, as far as we know, much higher than the values of state-of-art catalysts. Density functional theory calculations revealed that the encapsulated gold clusters effectively reduced the energy required for the dissociation of O-2 molecules, leading to the excellent catalytic activity. |
| WOS关键词 | LIQUID-PHASE OXIDATION ; CO OXIDATION ; MOLECULAR-OXYGEN ; SIZE ; NANOPARTICLES ; NANOCATALYSIS ; EMERGENCE ; LIGANDS ; SCIENCE ; TOLUENE |
| 资助项目 | Young Thousand Talented Program ; National Natural Science Foundation of China[21671073] ; National Natural Science Foundation of China[21621001] ; National Natural Science Foundation of China[21671074] ; 111 Project of the Ministry of Education of China[B17020] ; National Key Research and Development Program of China[2017YFA0204800] ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Program for JLU Science and Technology Innovative Research Team |
| WOS研究方向 | Chemistry ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000453489300021 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | Young Thousand Talented Program ; Young Thousand Talented Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project of the Ministry of Education of China ; 111 Project of the Ministry of Education of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Program for JLU Science and Technology Innovative Research Team ; Program for JLU Science and Technology Innovative Research Team ; Young Thousand Talented Program ; Young Thousand Talented Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project of the Ministry of Education of China ; 111 Project of the Ministry of Education of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Program for JLU Science and Technology Innovative Research Team ; Program for JLU Science and Technology Innovative Research Team ; Young Thousand Talented Program ; Young Thousand Talented Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project of the Ministry of Education of China ; 111 Project of the Ministry of Education of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Program for JLU Science and Technology Innovative Research Team ; Program for JLU Science and Technology Innovative Research Team ; Young Thousand Talented Program ; Young Thousand Talented Program ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; 111 Project of the Ministry of Education of China ; 111 Project of the Ministry of Education of China ; National Key Research and Development Program of China ; National Key Research and Development Program of China ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences, U.S. Department of Energy ; Program for JLU Science and Technology Innovative Research Team ; Program for JLU Science and Technology Innovative Research Team |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166494]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Dai, Sheng; Sun, Lei; Qiao, Zhen-An |
| 作者单位 | 1.Oak Ridge Natl Lab, Chem Sci Div, Oak Ridge, TN 37831 USA 2.Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Jilin, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Dai, Sheng,Liu, Yali,Zhang, Pengfei,et al. Gold Cluster-CeO2 Nanostructured Hybrid Architectures as Catalysts for Selective Oxidation of Inert Hydrocarbons[J]. CHEMISTRY OF MATERIALS,2018,30(23):8579-8586. |
| APA | Dai, Sheng.,Liu, Yali.,Zhang, Pengfei.,Liu, Junmin.,Wang, Tao.,...&Qiao, Zhen-An.(2018).Gold Cluster-CeO2 Nanostructured Hybrid Architectures as Catalysts for Selective Oxidation of Inert Hydrocarbons.CHEMISTRY OF MATERIALS,30(23),8579-8586. |
| MLA | Dai, Sheng,et al."Gold Cluster-CeO2 Nanostructured Hybrid Architectures as Catalysts for Selective Oxidation of Inert Hydrocarbons".CHEMISTRY OF MATERIALS 30.23(2018):8579-8586. |
入库方式： OAI收割
来源：大连化学物理研究所
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