Enantiodivergent Desymmetrization in the Rhodium( III)-Catalyzed Annulation of Sulfoximines with Diazo Compounds
文献类型：期刊论文
| 作者 | Wan, Boshun2; Shen, Bingxue1,2; Li, Xingwei2,3 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018-11-19 |
| 卷号 | 57期号:47页码:15534-15538 |
| 关键词 | asymmetric C-H activation desymmetrization enantiodivergence rhodium sulfoximes |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201810472 |
| 通讯作者 | Li, Xingwei(xwli@dicp.ac.cn) |
| 英文摘要 | Rh-III- and Ir-III-catalyzed asymmetric C-H functionalization reactions of arenes have relied on the employment of chiral Rh-III/Ir-III cyclopentadienyl catalysts, the introduction of chiral carboxylic acids to achiral Cp*RhX2 catalysts, and the integration of both strategies. Despite considerable progress, each reaction only provided a specific configuration of the enantioenriched product when using a particular chiral catalyst. Reported in this work is the enantiodivergent coupling of sulfoximines with various diazo compounds by Rh-III-catalyzed desymmetrizing annulation. The enantiodivergence was enabled by a judicious choice of achiral carboxylic acids, and the enantioselectivity correlates with the steric bias of the carboxylic acid and the sulfoximine. |
| WOS关键词 | C-H ACTIVATION ; N BOND ; ASYMMETRIC-SYNTHESIS ; 2+2+2 CYCLOADDITION ; FUNCTIONALIZATION ; LIGANDS ; COMBINATION ; CATALYSIS ; RH |
| 资助项目 | NSFC[21525208] ; NSFC[21472186] ; SNNU |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000453344500041 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | NSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU ; NSFC ; NSFC ; SNNU ; SNNU |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166496]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Xingwei |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 3.Shaanxi Normal Univ SNNU, Sch Chem & Chem Engn, Xian 710062, Shaanxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Wan, Boshun,Shen, Bingxue,Li, Xingwei. Enantiodivergent Desymmetrization in the Rhodium( III)-Catalyzed Annulation of Sulfoximines with Diazo Compounds[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(47):15534-15538. |
| APA | Wan, Boshun,Shen, Bingxue,&Li, Xingwei.(2018).Enantiodivergent Desymmetrization in the Rhodium( III)-Catalyzed Annulation of Sulfoximines with Diazo Compounds.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(47),15534-15538. |
| MLA | Wan, Boshun,et al."Enantiodivergent Desymmetrization in the Rhodium( III)-Catalyzed Annulation of Sulfoximines with Diazo Compounds".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.47(2018):15534-15538. |
入库方式： OAI收割
来源：大连化学物理研究所
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