Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines
文献类型：期刊论文
| 作者 | Li, Xincheng1; Yi, Ruxia1,2; Wan, Boshun1 |
| 刊名 | ORGANIC CHEMISTRY FRONTIERS
 |
| 出版日期 | 2018-12-07 |
| 卷号 | 5期号:23页码:3488-3493 |
| ISSN号 | 2052-4129 |
| DOI | 10.1039/c8qo00984h |
| 通讯作者 | Wan, Boshun(bswan@dicp.ac.cn) |
| 英文摘要 | Ring-opening and cyclization of aziridines with aryl azides in the presence of TfOH has been developed. This strategy enables the construction of 6-(triflyloxy)quinoline cores by utilizing aziridine as a two-carbon surrogate. The introduction of a trifyl group at the 6-position of quinoline would allow further construction of carbon-carbon and carbon-heteroatom bonds in the cross-coupling reactions. |
| WOS关键词 | FORMAL 3+2+2 CYCLOADDITION ; POT 3-COMPONENT SYNTHESIS ; CROSS-COUPLING REACTIONS ; N-ACTIVATED AZIRIDINES ; C-H OXIDATION ; 2,3-DISUBSTITUTED QUINOLINES ; POVAROV REACTION ; ENANTIOSELECTIVE SYNTHESIS ; CATALYZED CYCLIZATION ; HIGHLY EFFICIENT |
| 资助项目 | National Natural Science Foundation of China[21772194] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000450737800020 |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166524]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Wan, Boshun |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xincheng,Yi, Ruxia,Wan, Boshun. Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines[J]. ORGANIC CHEMISTRY FRONTIERS,2018,5(23):3488-3493. |
| APA | Li, Xincheng,Yi, Ruxia,&Wan, Boshun.(2018).Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines.ORGANIC CHEMISTRY FRONTIERS,5(23),3488-3493. |
| MLA | Li, Xincheng,et al."Ring-opening and cyclization of aziridines with aryl azides: metal-free synthesis of 6-(triflyloxy)quinolines".ORGANIC CHEMISTRY FRONTIERS 5.23(2018):3488-3493. |
入库方式： OAI收割
来源：大连化学物理研究所
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