Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications
文献类型：期刊论文
| 作者 | Zhang, Jiangwei1,2,3; Huang, Yichao2; Li, Gao1,3; Wei, Yongge2 |
| 刊名 | COORDINATION CHEMISTRY REVIEWS
 |
| 出版日期 | 2019 |
| 卷号 | 378页码:395-414 |
| 关键词 | Polyoxometalates POMs-based materials Alkoxylation Organic functionalization Tris ligands |
| ISSN号 | 0010-8545 |
| DOI | 10.1016/j.ccr.2017.10.025 |
| 通讯作者 | Li, Gao(gaoli@dicp.ac.cn) ; Wei, Yongge(yonggewei@mail.tsinghua.edu.cn) |
| 英文摘要 | Polyoxometalates (POMs), an exceptional family of coordination clusters consisting of Mo, W, V, etc. early transition metal ions in their highest oxidation states, have received significant attention over recent years due to their structural versatility and unique and diverse chemical and physical properties. The functionalization of POMs with organic ligands provides a novel strategy to precisely incorporate POMs with advanced functional organic moieties on their surfaces and enhance their compatibility in organic media. Among the various organically functionalized synthetic strategies for POM-based organic-inorganic hybrid materials, alkoxylation of POMs stands for one of the hottest topics during the past decades, since the diverse and tunable alkoxyl ligands are able to anchor on the surface of many POMs clusters, forming novel and flexible organically functionalized POM clusters, which can be further exploited as building blocks to design various functionalized POM-based hybrids with charming catalytic properties, and biomedicine, energy, or functional materials applications. In this review, recent advances in alkoxylation chemistry of POMs from synthetic strategies, structural overviews to their functional applications have been discussed. (C) 2017 Elsevier B.V. All rights reserved. |
| WOS关键词 | ANDERSON-TYPE POLYOXOMETALATE ; MIXED-VALENCE ; ORGANIC HYBRID ; POST-FUNCTIONALIZATION ; HETEROGENEOUS CATALYSTS ; ORGANOIMIDO DERIVATIVES ; CONTROLLABLE SYNTHESIS ; ASSISTED SYNTHESIS ; HEXAMETALATE CORE ; BUILDING-BLOCKS |
| 资助项目 | National Natural Science Foundation of China (NSFC)[21471087] ; National Natural Science Foundation of China (NSFC)[21631007] ; National Natural Science Foundation of China (NSFC)[21225103] ; National Natural Science Foundation of China (NSFC)[21701168] ; Liaoning Natural Science Foundation[20170540897] ; fund of the Thousand Youth Talents Plan |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000451498300022 |
| 出版者 | ELSEVIER SCIENCE SA |
| 资助机构 | National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan ; National Natural Science Foundation of China (NSFC) ; National Natural Science Foundation of China (NSFC) ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; fund of the Thousand Youth Talents Plan ; fund of the Thousand Youth Talents Plan |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166574]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Gao; Wei, Yongge |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 2.Tsinghua Univ, Dept Chem, Minist Educ, Key Lab Organ Optoelect & Mol Engn, Beijing 100084, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, Gold Catalysis Res Ctr, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jiangwei,Huang, Yichao,Li, Gao,et al. Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications[J]. COORDINATION CHEMISTRY REVIEWS,2019,378:395-414. |
| APA | Zhang, Jiangwei,Huang, Yichao,Li, Gao,&Wei, Yongge.(2019).Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications.COORDINATION CHEMISTRY REVIEWS,378,395-414. |
| MLA | Zhang, Jiangwei,et al."Recent Recent advances in alkoxylation chemistry of polyoxometalates: From synthetic strategies, structural overviews to functional applications".COORDINATION CHEMISTRY REVIEWS 378(2019):395-414. |
入库方式： OAI收割
来源：大连化学物理研究所
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