Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds
文献类型：期刊论文
| 作者 | Liu, Liang; Xi, Zhenfeng |
| 刊名 | CHINESE JOURNAL OF CHEMISTRY
 |
| 出版日期 | 2018-12-01 |
| 卷号 | 36期号:12页码:1213-1221 |
| 关键词 | structure elucidation copper reactive intermediate organocopper(III) organocuprate(III) reductive elimination |
| ISSN号 | 1001-604X |
| DOI | 10.1002/cjoc.201800365 |
| 通讯作者 | Liu, Liang(liang.liu@pku.edu.cn) ; Xi, Zhenfeng(zfxi@pku.edu.cn) |
| 英文摘要 | Reductive elimination around Cu(III) atom arises an increasing attention, since this organometallic pathway has been often proposed in a range of Cu-based reactions. However, due to limited organocopper(III) compounds with well-defined structures, this elementary reaction still remains an extremely challenging issue. In this review, structurally well-defined organocopper(III) compounds are mainly divided into three classes based on their ligands: perfluoromethyl Cu(III) compounds, macrocyclic ligand-based aryl-Cu(III) compounds, and spiro organocopper(III) compounds chelated by bidentate ligands. The majority of organocopper(III) compounds display the typical square planar geometry. There also exist a few penta-coordinated organocopper(III) complexes, which share a weak apical Cu-L bond. In order to form a cis Cu(III)-C and Cu(III)-Nu bonding geometry required for reductive elimination, the re-arrangement of coordination modes around tetra-coordinated Cu(III) atoms is necessary. For the aryl-Cu(III) cationic complexes with one Cu(III)-C bond, the re-arrangement is triggered by the coordination of the fifth ligand (solvent or nucleophiles), while for the tetra-carbon-coordinated organocuprate(III) compounds, the process might be realized via the cleavage of one Cu(III)-C bond by attack of electrophiles. Stoichiometric and catalytic reactions involving well-defined organocopper(III) compounds to form C-C or C-heteroatom bonds are discussed to support their intermediacy. |
| WOS关键词 | TRANSITION-METAL-COMPLEXES ; CROSS-COUPLING REACTIONS ; N-CONFUSED PORPHYRINS ; RAPID INJECTION NMR ; X-RAY-STRUCTURE ; H BOND ; TRIFLUOROMETHYL COMPLEXES ; CONJUGATE ADDITION ; CATALYTIC CYCLE ; COPPER(III) INTERMEDIATE |
| 资助项目 | National Natural Science Foundation of China[21690061] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000450017200020 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166688]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Liang; Xi, Zhenfeng |
| 作者单位 | Peking Univ, Key Lab Bioorgan Chem & Mol Engn, BNLMS, Minist Educ,Coll Chem, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Liu, Liang,Xi, Zhenfeng. Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds[J]. CHINESE JOURNAL OF CHEMISTRY,2018,36(12):1213-1221. |
| APA | Liu, Liang,&Xi, Zhenfeng.(2018).Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds.CHINESE JOURNAL OF CHEMISTRY,36(12),1213-1221. |
| MLA | Liu, Liang,et al."Organocopper(III) Compounds with Well-defined Structures Undergo Reductive Elimination to Form C-C or C-Heteroatom Bonds".CHINESE JOURNAL OF CHEMISTRY 36.12(2018):1213-1221. |
入库方式： OAI收割
来源：大连化学物理研究所
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