Diphosphine-induced chiral propeller arrangement of gold nanoclusters for singlet oxygen photogeneration
文献类型：期刊论文
| 作者 | Zhang, Jiangwei2; Zhou, Yang2,3; Zheng, Kai2; Abroshan, Hadi4; Kauffman, Douglas R.1; Sun, Junliang5; Li, Gao2 |
| 刊名 | NANO RESEARCH
 |
| 出版日期 | 2018-11-01 |
| 卷号 | 11期号:11页码:5787-5798 |
| ISSN号 | 1998-0124 |
| 关键词 | gold nanoclusters Au-13 chirality singlet oxygen synchrotron radiation X-ray diffraction (XRD) |
| DOI | 10.1007/s12274-017-1935-2 |
| 通讯作者 | Li, Gao(gaoli@dicp.ac.cn) |
| 英文摘要 | In this study, 1,2-bis(diphenylphosphino)ethane (dppe) ligands are used to synthesize gold nanoclusters with an icosahedral Au-13 core. The nanoclusters are characterized and formulated as [Au-13(dppe)5Cl(2)]Cl-3 using synchrotron radiation X-ray diffraction, UV/Vis absorption spectroscopy, electrospray ionization mass spectrometry, and density functional theory (DFT) calculations. The bidentate feature of dppe ligands and the positions of coordinating surface gold atoms induce a helical arrangement that forms a propeller-like structure, which reduces the symmetry of the gold nanocluster to C-1. Therefore, dppe ligands perform as a directing agent to create chiral an ansa metallamacrocycle [Au-13(dppe)(5)Cl-2](3+) nanocluster, as confirmed by simulated electronic circular dichroism spectrum. The highest occupied molecular orbital (HOMO)-lowest unoccupied molecular orbital (LUMO) gap of the [Au-13(dppe)(5)Cl-2](3+) cluster is determined as approx. 1.9 eV, and further confirmed by ultraviolet photoemission spectroscopy analysis and DFT simulation. Furthermore, the photoactivity of [Au-13(dppe)(5)Cl-2](3+) is investigated, with the nanocluster shown to possess near-infrared photoluminescence properties, which can be employed for O-1(2) photogeneration. The quantum yield of O-1(2) photogeneration using the [Au-13(dppe)(5)Cl-2](3+) nanocluster is up to 0.71, which is considerably higher than those of anthracene (an organic dye), and Au-25 and Au-38 nanoclusters. |
| WOS关键词 | NUMBER AU-13 CLUSTERS ; AEROBIC OXIDATION ; ANDERSON-TYPE ; EXCHANGE ; LIGANDS ; NANOPARTICLES ; PHOTOCATALYST ; GENERATION ; CHEMISTRY ; CATALYSIS |
| 资助项目 | National Natural Science Foundation of China[21701168] ; Liaoning Natural Science Foundation[20170540897] |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics ; Materials Science ; Physics |
| 语种 | 英语 |
| 出版者 | TSINGHUA UNIV PRESS |
| WOS记录号 | WOS:000449842500002 |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Liaoning Natural Science Foundation ; Liaoning Natural Science Foundation |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166720]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Gao |
| 作者单位 | 1.US DOE, Natl Energy Technol Lab, Pittsburgh, PA 15236 USA 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 4.Stanford Univ, Dept Chem Engn, SUNCAT Ctr Interface Sci & Catalysis, 443 Via Ortega, Stanford, CA 94305 USA 5.Peking Univ, Beijing Natl Lab Mol Sci, Coll Chem & Mol Engn, State Key Lab Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Jiangwei,Zhou, Yang,Zheng, Kai,et al. Diphosphine-induced chiral propeller arrangement of gold nanoclusters for singlet oxygen photogeneration[J]. NANO RESEARCH,2018,11(11):5787-5798. |
| APA | Zhang, Jiangwei.,Zhou, Yang.,Zheng, Kai.,Abroshan, Hadi.,Kauffman, Douglas R..,...&Li, Gao.(2018).Diphosphine-induced chiral propeller arrangement of gold nanoclusters for singlet oxygen photogeneration.NANO RESEARCH,11(11),5787-5798. |
| MLA | Zhang, Jiangwei,et al."Diphosphine-induced chiral propeller arrangement of gold nanoclusters for singlet oxygen photogeneration".NANO RESEARCH 11.11(2018):5787-5798. |
入库方式： OAI收割
来源：大连化学物理研究所
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