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Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity

文献类型：期刊论文

作者Liu, Jiayi2,5; Li, Xuning2; Liu, Biao3; Zhao, Chunxiao1,2; Kuang, Zhichong2,5; Hu, Ruisheng1; Liu, Bin4; Ao, Zhimin3; Wang, Junhu2
刊名ACS APPLIED MATERIALS & INTERFACES
出版日期2018-11-07
卷号10期号:44页码:38051-38056
关键词secondary building units shape-controlled Prussian blue analogue DFT calculation Fenton reaction
ISSN号1944-8244
DOI10.1021/acsami.8b12686
通讯作者Liu, Bin(LiuBin@ntu.edu.sg) ; Ao, Zhimin(zhimin.ao@gdut.edu.cn) ; Wang, Junhu(wangjh@dicp.ac.cn)
英文摘要Controllable synthesis of metal-organic frameworks with well-defined morphology, composition, and size is of great importance toward understanding their structure-property relationship in various applications. Herein, we demonstrate a general strategy to modulate the relative growth rate of the secondary building units (SBUs) along different crystal facets for the synthesis of Fe-Co, Mn0.5Fe0.5-Co, and Mn-Co Prussian blue analogues (PBAs) with tunable morphologies. The same growth rate of SBUs along the {100}, {110}, and {111} surfaces at 0 degrees C results in the formation of spherical PBA particles, while the lowest growth rate of SBUs along the {100} surface resulting from the highest surface energy with increasing reaction temperature induces the formation of PBA cubes. Fenton reaction was used as the model reaction to probe the structure-catalytic activity relation for the as-synthesized catalysts. The cubic Fe-Co PBA was found to exhibit the best catalytic performance with reaction rate constant 6 times higher than that of the spherical counterpart. Via density functional theory calculations, the abundant enclosed {100} facets in cubic Fe-Co PBA were identified to have the highest surface energy and favor high Fenton reaction activity.
WOS关键词PRUSSIAN BLUE ANALOGS ; POROUS COORDINATION POLYMERS ; BISPHENOL-A ; HYDROGEN STORAGE ; CO ; PEROXYMONOSULFATE ; DEGRADATION ; FE ; ACTIVATION ; MECHANISM
资助项目National Natural Science Foundation of China[21476232] ; National Natural Science Foundation of China[21607029] ; National Natural Science Foundation of China[21777033] ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics[N-16-07] ; China Ministry of Science and Technology[2016YFA0202804] ; Science and Technology Program of Guangdong Province[2017B020216003] ; Science and Technology Program of Guangzhou City[201707010359] ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology
WOS研究方向Science & Technology - Other Topics ; Materials Science
语种英语
WOS记录号WOS:000449887600031
出版者AMER CHEMICAL SOC
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; fund of the State Key Laboratory of Catalysis in Dalian Institute of Chemical Physics ; China Ministry of Science and Technology ; China Ministry of Science and Technology ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangdong Province ; Science and Technology Program of Guangzhou City ; Science and Technology Program of Guangzhou City ; 1000 plan for Young Professionals' Program of China ; 1000 plan for Young Professionals' Program of China ; 100 talents Program of Guangdong University of Technology ; 100 talents Program of Guangdong University of Technology
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166722]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Liu, Bin; Ao, Zhimin; Wang, Junhu
作者单位1.Inner Mongolia Univ, Coll Chem & Chem Engn, Hohhot 010021, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, Mossbauer Effect Data Ctr, Dalian 116023, Peoples R China
3.Guangdong Univ Technol, Sch Environm Sci & Engn, Inst Environm Hlth & Pollut Control, Guangzhou Key Lab Environm Catalysis & Pollut Con, Guangzhou 510006, Guangdong, Peoples R China
4.Nanyang Technol Univ, Sch Chem & Biomed Engn, 62 Nanyang Dr, Singapore 637459, Singapore
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Liu, Jiayi,Li, Xuning,Liu, Biao,et al. Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(44):38051-38056.
APA Liu, Jiayi.,Li, Xuning.,Liu, Biao.,Zhao, Chunxiao.,Kuang, Zhichong.,...&Wang, Junhu.(2018).Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity.ACS APPLIED MATERIALS & INTERFACES,10(44),38051-38056.
MLA Liu, Jiayi,et al."Shape-Controlled Synthesis of Metal-Organic Frameworks with Adjustable Fenton-Like Catalytic Activity".ACS APPLIED MATERIALS & INTERFACES 10.44(2018):38051-38056.

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来源：大连化学物理研究所

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