C-C Bonds Cleavage of Biomass-Derived Glycerol to Methane and Ethylene Glycol in Aqueous Phase Over Highly Dispersed Ru-Based Catalysts
文献类型：期刊论文
| 作者 | Xu, Jie2; Huang, Qian-Qian1,2; Yu, Wei-Qiang2; Luo, Xiao-Lin1,2; Gao, Jin2 |
| 刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2018-10-01 |
| 卷号 | 7期号:10页码:2039-2044 |
| 关键词 | carbothermal reduction highly dispersed Ru NPs glycerol hydrogenolysis C-C bond cleavage |
| ISSN号 | 2193-5807 |
| DOI | 10.1002/ajoc.201800505 |
| 通讯作者 | Yu, Wei-Qiang(yuweiqiang@dicp.ac.cn) ; Xu, Jie(xujie@dicp.ac.cn) |
| 英文摘要 | An alternative method for the conversion of crude glycerol was proposed to produce renewable energy methane and high-value chemical ethylene glycol through preferential cleavage of C-C bonds, catalyzed by highly dispersed Ru-based catalysts prepared by carbothermal reduction. It was found that the Ru particles size could be tuned by adjusting the reduction temperature, and the size firstly decreased then increased with raising of the temperature of carbothermal reduction. This resulted in the opposite tendency of catalytic performance against the Ru particle sizes in hydrogenolysis of glycerol, in which the glycerol conversion and yield of C-C bond cleavage increased firstly and then decreased. Ru catalysts carbothermal reduced at 450 degrees C possessed highly dispersed Ru nanoparticles with uniform particle sizes about 1.0nm that showed high hydrogenation activity and selectivity of C-C bond cleavage as well as good stability that could be recycled in aqueous phase hydrogenolysis of glycerol. |
| WOS关键词 | ORDERED MESOPOROUS CARBON ; FISCHER-TROPSCH SYNTHESIS ; METAL NANOPARTICLES ; NI CATALYSTS ; HYDROGENOLYSIS ; HYDROGENATION ; DEACTIVATION ; PERFORMANCE ; SUPPORT ; HYDRODEOXYGENATION |
| 资助项目 | National Natural Science Foundation of China[21790331] ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration[XDA21030400] ; Dalian Young Star of Science and Technology Project[2017RQ115] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000447542200009 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Strategic Priority Research Program of the Chinese Academy of Sciences Transformational Technologies for Clean Energy and Demonstration ; Dalian Young Star of Science and Technology Project ; Dalian Young Star of Science and Technology Project |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166784]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Xu, Jie; Yu, Wei-Qiang |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Jie,Huang, Qian-Qian,Yu, Wei-Qiang,et al. C-C Bonds Cleavage of Biomass-Derived Glycerol to Methane and Ethylene Glycol in Aqueous Phase Over Highly Dispersed Ru-Based Catalysts[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2018,7(10):2039-2044. |
| APA | Xu, Jie,Huang, Qian-Qian,Yu, Wei-Qiang,Luo, Xiao-Lin,&Gao, Jin.(2018).C-C Bonds Cleavage of Biomass-Derived Glycerol to Methane and Ethylene Glycol in Aqueous Phase Over Highly Dispersed Ru-Based Catalysts.ASIAN JOURNAL OF ORGANIC CHEMISTRY,7(10),2039-2044. |
| MLA | Xu, Jie,et al."C-C Bonds Cleavage of Biomass-Derived Glycerol to Methane and Ethylene Glycol in Aqueous Phase Over Highly Dispersed Ru-Based Catalysts".ASIAN JOURNAL OF ORGANIC CHEMISTRY 7.10(2018):2039-2044. |
入库方式： OAI收割
来源：大连化学物理研究所
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