Efficient synthesis of 5-hydroxymethylfurfural from mannose with a reusable MCM-41-supported tin catalyst
文献类型：期刊论文
| 作者 | Xu, Zhanwei2; Jia, Songyan1; He, Xinjun1; Ma, Jiao1; Wang, Kangjun1; Zhang, Z. Conrad2 |
| 刊名 | CATALYSIS SCIENCE & TECHNOLOGY
 |
| 出版日期 | 2018-11-07 |
| 卷号 | 8期号:21页码:5526-5534 |
| ISSN号 | 2044-4753 |
| DOI | 10.1039/c8cy01630e |
| 通讯作者 | Jia, Songyan(jiasongyan@126.com) ; Zhang, Z. Conrad(zczhang@yahoo.com) |
| 英文摘要 | The synthesis of furan compounds by renewable carbohydrates has emerged as an important path toward biomass utilization. 5-Hydroxymethylfurfural (5-HMF) and furfural are two typical furan products from cellulosic and hemicellulosic materials, of which the primary components (hexoses and pentoses) undergo selective dehydration. It is worth noting that hemicellulose is rich in not only pentoses but also hexoses, indicating the feasibility of producing 5-HMF and furfural simultaneously. However, research on the production of 5-HMF from hemicellulose-derived hexoses remains lacking. Mannose, a major hexose component of hemicellulose, has been previously found to be a suitable feedstock for 5-HMF production in the presence of homogeneous catalysts, such as metal salts. In this work, Cr-, Al- and Sn/MCM-41 catalysts were prepared by a simple impregnation method and characterized. The conversion of mannose into 5-HMF was evaluated in dimethyl sulfoxide (DMSO) solvent. It was found that the as-synthesized Sn/MCM-41 catalyst showed a superior activity to Cr/MCM-41 and Al/MCM-41. Mannose could be effectively converted into 5-HMF with a yield of approximate to 45% and approximate to 88% conversion at 150 degrees C after 60 min, which were comparable to reported results over heterogeneous catalysts. The as-synthesized Sn/MCM-41 catalyst was also efficient for the conversion of glucose and fructose with reasonable 5-HMF yields. The Sn/MCM-41 catalyst could be reused for eight consecutive cycles without significant loss of catalytic activity. |
| WOS关键词 | ALUMINUM SALT CATALYST ; IONIC LIQUID ; HETEROGENEOUS CATALYST ; ONE-POT ; SELECTIVE DEHYDRATION ; GLUCOSE CONVERSION ; ALDOL CONDENSATION ; MESOPOROUS MCM-41 ; LEVULINIC ACID ; CYCLIC-KETONES |
| 资助项目 | Natural Science Foundation of Liaoning Province (China)[2015020633] ; Department of Education of Liaoning Province (China)[L2015421] ; National Natural Science Foundation of China[21306186] ; National Natural Science Foundation of China[21721004] ; National Natural Science Foundation of China[21706255] ; CAS/SAFEA International Partnership Program for Creative Research Teams |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| 出版者 | ROYAL SOC CHEMISTRY |
| WOS记录号 | WOS:000448661800016 |
| 资助机构 | Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams ; Natural Science Foundation of Liaoning Province (China) ; Natural Science Foundation of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; Department of Education of Liaoning Province (China) ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; CAS/SAFEA International Partnership Program for Creative Research Teams ; CAS/SAFEA International Partnership Program for Creative Research Teams |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166796]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Jia, Songyan; Zhang, Z. Conrad |
| 作者单位 | 1.Shenyang Univ Chem Technol, Coll Chem Engn, Shenyang 110142, Liaoning, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Xu, Zhanwei,Jia, Songyan,He, Xinjun,et al. Efficient synthesis of 5-hydroxymethylfurfural from mannose with a reusable MCM-41-supported tin catalyst[J]. CATALYSIS SCIENCE & TECHNOLOGY,2018,8(21):5526-5534. |
| APA | Xu, Zhanwei,Jia, Songyan,He, Xinjun,Ma, Jiao,Wang, Kangjun,&Zhang, Z. Conrad.(2018).Efficient synthesis of 5-hydroxymethylfurfural from mannose with a reusable MCM-41-supported tin catalyst.CATALYSIS SCIENCE & TECHNOLOGY,8(21),5526-5534. |
| MLA | Xu, Zhanwei,et al."Efficient synthesis of 5-hydroxymethylfurfural from mannose with a reusable MCM-41-supported tin catalyst".CATALYSIS SCIENCE & TECHNOLOGY 8.21(2018):5526-5534. |
入库方式： OAI收割
来源：大连化学物理研究所
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