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Co(III)/Zn(II)-catalyzed dearomatization of indoles and coupling with carbenes from ene-yne ketones via intramolecular cyclopropanation

文献类型：期刊论文

作者Li, Na1,2; Li, Xingwei1,3; Chang, Junbiao1; Kong, Lingheng3; Wang, Shuangjing1; Wang, Dandan1; Cheng, Miao1
刊名CHINESE JOURNAL OF CATALYSIS
出版日期2018-12-01
卷号39期号:12页码:1881-1889
关键词Co(III)/Zn(II) catalysis Dearomatization Cyclopropanation Carbene Indole
ISSN号0253-9837
DOI10.1016/S1872-2067(18)63154-7
通讯作者Chang, Junbiao(changjunbiao@zzu.edu.cn) ; Li, Xingwei(xwli@dicp.ac.cn)
英文摘要A straightforward and efficient protocol for dearomatizing indoles is described. The reaction, catalyzed by an inexpensive Co(III)/Zn(II) catalyst, starts from easily accessible N-pyrimidinyl indoles and ene-yne ketones. Mild reaction conditions, high diastereoselectivity, a broad substrate scope, effective functional group tolerance, and reasonable to remarkable yields were observed. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
WOS关键词C-H ACTIVATION ; ENANTIOSPECIFIC TOTAL-SYNTHESIS ; METAL-CATALYZED REACTION ; (2-FURYL)CARBENE COMPLEXES ; STEREOSELECTIVE-SYNTHESIS ; CARBONYL-COMPOUNDS ; 3+2 CYCLOADDITION ; ORGANIC-SYNTHESIS ; N-HETEROCYCLES ; ALKALOID-G
资助项目National Natural Science Foundation of China[21525208] ; National Natural Science Foundation of China[21472186] ; Henan Normal University[5101034011009]
WOS研究方向Chemistry ; Engineering
语种英语
WOS记录号WOS:000447958600003
出版者SCIENCE PRESS
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; Henan Normal University ; Henan Normal University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Henan Normal University ; Henan Normal University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Henan Normal University ; Henan Normal University ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; Henan Normal University ; Henan Normal University
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166848]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Li, Xingwei; Chang, Junbiao
作者单位1.Henan Normal Univ, Henan Key Lab Organ Funct Mol & Drug Innovat, Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China
2.Xinxiang Med Univ, Sch Pharm, Xinxiang 453003, Henan, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714		 Li, Na,Li, Xingwei,Chang, Junbiao,et al. Co(III)/Zn(II)-catalyzed dearomatization of indoles and coupling with carbenes from ene-yne ketones via intramolecular cyclopropanation[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(12):1881-1889.
APA Li, Na.,Li, Xingwei.,Chang, Junbiao.,Kong, Lingheng.,Wang, Shuangjing.,...&Cheng, Miao.(2018).Co(III)/Zn(II)-catalyzed dearomatization of indoles and coupling with carbenes from ene-yne ketones via intramolecular cyclopropanation.CHINESE JOURNAL OF CATALYSIS,39(12),1881-1889.
MLA Li, Na,et al."Co(III)/Zn(II)-catalyzed dearomatization of indoles and coupling with carbenes from ene-yne ketones via intramolecular cyclopropanation".CHINESE JOURNAL OF CATALYSIS 39.12(2018):1881-1889.

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来源：大连化学物理研究所

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