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Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control

文献类型：期刊论文

作者Zhou, Xukai1,2; Li, Xingwei1; Sun, Jiaqiong1
刊名CHINESE JOURNAL OF CATALYSIS
出版日期2018-11-01
卷号39期号:11页码:1782-1791
关键词Rh(III)-catalysis Chemo-selectivity Annulation Substrate control Condition control
ISSN号0253-9837
DOI10.1016/S1872-2067(18)63134-1
通讯作者Li, Xingwei(xwli@dicp.ac.cn)
英文摘要Rh(III)-catalyzed C-H activation of N-protected anilines and chemo-divergent couplings with acroleins/enones have been realized for synthesis of three classes of heterocycles. The oxidative coupling of N-pyridylaniline afforded dihydroquinolones with the acrolein being a major hydrogen acceptor. When the directing group was replaced by pyrimidyl in the same system, redox-neutral coupling occurred to afford hemiaminal ethers. Oxidative annulation of N-pyridylanilines with enones using AgBF4 oxidant afforded atropisomeric quinolinium salts. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved.
WOS关键词C-H ACTIVATION ; TRANSFER HYDROGENATION ; BOND ACTIVATION ; ALPHA,BETA-UNSATURATED ALDEHYDES ; DIRECT FUNCTIONALIZATION ; QUINOLIZIDINE ALKALOIDS ; NITROGEN-HETEROCYCLES ; ALCOHOL OXIDATION ; RHODIUM CATALYSIS ; DIRECTING GROUP
资助项目National Nature Science Foundation of China[21525208] ; National Nature Science Foundation of China[21472186] ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
WOS研究方向Chemistry ; Engineering
语种英语
WOS记录号WOS:000447958500008
出版者SCIENCE PRESS
资助机构National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; National Nature Science Foundation of China ; National Nature Science Foundation of China ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; fund for new technology of methanol conversion of Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166870]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Li, Xingwei
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
推荐引用方式
GB/T 7714		 Zhou, Xukai,Li, Xingwei,Sun, Jiaqiong. Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(11):1782-1791.
APA Zhou, Xukai,Li, Xingwei,&Sun, Jiaqiong.(2018).Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control.CHINESE JOURNAL OF CATALYSIS,39(11),1782-1791.
MLA Zhou, Xukai,et al."Chemo-selective couplings of anilines and acroleins/enones under substrate control and condition control".CHINESE JOURNAL OF CATALYSIS 39.11(2018):1782-1791.

入库方式： OAI收割

来源：大连化学物理研究所

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