Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives
文献类型：期刊论文
| 作者 | Lou, Ning1; Kraevaya, Olga A.4; Gan, Liangbing1,2; Troshin, Pavel A.3,4 |
| 刊名 | SYNTHESIS-STUTTGART
 |
| 出版日期 | 2018-11-01 |
| 卷号 | 50期号:21页码:4283-4289 |
| 关键词 | fullerene amination pyrrole substituent effect nucleophilic aromatic substitution |
| ISSN号 | 0039-7881 |
| DOI | 10.1055/s-0037-1610220 |
| 通讯作者 | Troshin, Pavel A.(troshin2003@inbox.ru) ; Gan, Liangbing(gan@pku.edu.cn) |
| 英文摘要 | Unlike the facile addition of aliphatic amines to fullerenes, heteroaromatic compounds with NH group do not react directly with pristine fullerenes. The present work reports the preparation of several cyclopentadienyl type [60]fullerene derivatives with pyrazole and pyrrole addends through replacement reactions of C (60) Cl (6) in the presence of tetrabutylammonium bromide. The method has also been applied for the synthesis of aniline and methoxyamine [60]fullerene cyclopentadienyl type adducts. Radical species were involved in the reaction mechanism. |
| WOS关键词 | ELECTROPHILIC AROMATIC-SUBSTITUTION ; CHLOROFULLERENE C60CL6 ; FULLERENE DERIVATIVES ; TERTIARY-AMINES ; ALIPHATIC-AMINES ; C-60 ; FUNCTIONALIZATION ; PHOTOADDITION ; PRECURSORS ; REACTIVITY |
| 资助项目 | NNSFC[21672009] ; MOST[2015CB856600] ; RFBR[16-53-52030] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000447714400011 |
| 出版者 | GEORG THIEME VERLAG KG |
| 资助机构 | NNSFC ; NNSFC ; MOST ; MOST ; RFBR ; RFBR ; NNSFC ; NNSFC ; MOST ; MOST ; RFBR ; RFBR ; NNSFC ; NNSFC ; MOST ; MOST ; RFBR ; RFBR ; NNSFC ; NNSFC ; MOST ; MOST ; RFBR ; RFBR |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166894]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gan, Liangbing; Troshin, Pavel A. |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 3.Skolkovo Inst Sci & Technol, Nobel St 3, Moscow 143026, Russia 4.Russian Acad Sci, Inst Problems Chem Phys, Semenov Prospect 1, Chernogolovka 142432, Moscow Region, Russia |
| 推荐引用方式 GB/T 7714 | Lou, Ning,Kraevaya, Olga A.,Gan, Liangbing,et al. Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives[J]. SYNTHESIS-STUTTGART,2018,50(21):4283-4289. |
| APA | Lou, Ning,Kraevaya, Olga A.,Gan, Liangbing,&Troshin, Pavel A..(2018).Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives.SYNTHESIS-STUTTGART,50(21),4283-4289. |
| MLA | Lou, Ning,et al."Synthesis of Pentapyrazolyl, Pentapyrrolyl, and Pentaanilino C (60) Derivatives".SYNTHESIS-STUTTGART 50.21(2018):4283-4289. |
入库方式： OAI收割
来源：大连化学物理研究所
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