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Progress and prospect for NASICON-type Na3V2(PO4)(3) for electrochemical energy storage

文献类型：期刊论文

作者Yi, Hongming2,3; Zhang, Huamin1,3; Zheng, Qiong3; Li, Xianfeng1,3
刊名JOURNAL OF ENERGY CHEMISTRY
出版日期2018-11-01
卷号27期号:6页码:1597-1617
关键词Sodium ion batteries Na3V2(PO4)(3) Crystal structure Electrical conductivity Energy storage
ISSN号2095-4956
DOI10.1016/j.jechem.2018.05.001
通讯作者Zheng, Qiong(zhengqiong@dicp.ac.cn) ; Zhang, Huamin(zhanghm@dicp.ac.cn)
英文摘要Sodium-ion batteries (SIBs) have attracted increasing attention in the past decades, because of high overall abundance of precursors, their even geographical distribution, and low cost. Na3V2(PO4)(3) (NVP), a typical sodium super ion conductor (NASICON)-based electrode material, exhibits pronounced structural stability, exceptionally high ion conductivity, rendering it a most promising electrode for sodium storage. However, the comparatively low electronic conductivity makes the theoretical capacity of NVP cannot be fully accessible even at comparatively low rates, presenting a major drawback for further practical applications, especially when high rate capability is especially important. Thus, many endeavors have been conformed to increase the surface and intrinsic electrical conductivity of NVP by coating the active materials with a conductive carbon layer, downsizing the NVP particles, combining the NVP particle with various carbon materials and ion doping strategy. In this review, to get a better understanding on the sodium storage in NVP, we firstly present 4 distinct crystal structures in the temperature range of -30 degrees C similar to 225 degrees C namely alpha-NVP, beta-NVP, beta'-NVP and gamma-NVP. Moreover, we give an overview of recent approaches to enhance the surface electrical conductivity and intrinsic electrical conductivity of NVP. Finally, some potential applications of NVP such as in all-climate environment and PHEV, EV fields have been prospected. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
WOS关键词SODIUM-ION BATTERIES ; LI3V2(PO4)(3) CATHODE MATERIALS ; CARBON-COATED NA3V2(PO4)(3) ; HIGH-RATE PERFORMANCE ; DOPED LI3V2(PO4)(3) ; ELECTRODE MATERIALS ; GRAPHENE NANOCOMPOSITES ; RECHARGEABLE BATTERY ; RATE CAPABILITY ; HIGH-CAPACITY
资助项目National Natural Science Foundation of China[21501171] ; National Natural Science Foundation of China[51403209] ; National Natural Science Foundation of China[21406221] ; National Natural Science Foundation of China[51177156/E0712]
WOS研究方向Chemistry ; Energy & Fuels ; Engineering
语种英语
WOS记录号WOS:000445109200007
出版者ELSEVIER SCIENCE BV
资助机构National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166918]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Zhang, Huamin; Zheng, Qiong
作者单位1.Collaborat Innovat Ctr Chem Energy Mat iChEM, Dalian 116023, Liaoning, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100039, Peoples R China
3.Chinese Acad Sci, Dalian Inst Chem Phys, Div Energy Storage, Dalian 116023, Liaoning, Peoples R China
推荐引用方式
GB/T 7714		 Yi, Hongming,Zhang, Huamin,Zheng, Qiong,et al. Progress and prospect for NASICON-type Na3V2(PO4)(3) for electrochemical energy storage[J]. JOURNAL OF ENERGY CHEMISTRY,2018,27(6):1597-1617.
APA Yi, Hongming,Zhang, Huamin,Zheng, Qiong,&Li, Xianfeng.(2018).Progress and prospect for NASICON-type Na3V2(PO4)(3) for electrochemical energy storage.JOURNAL OF ENERGY CHEMISTRY,27(6),1597-1617.
MLA Yi, Hongming,et al."Progress and prospect for NASICON-type Na3V2(PO4)(3) for electrochemical energy storage".JOURNAL OF ENERGY CHEMISTRY 27.6(2018):1597-1617.

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来源：大连化学物理研究所

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