Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2
文献类型：期刊论文
| 作者 | Lu, Xing2; Gan, Liangbing1,3; Li, Yanbang1; Lou, Ning1; Xu, Dan1; Pan, Changwang2 |
| 刊名 | ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
 |
| 出版日期 | 2018-10-22 |
| 卷号 | 57期号:43页码:14144-14148 |
| 关键词 | encapsulation fullerenes hydrogen peroxide molecular containers open-cage fullerenes |
| ISSN号 | 1433-7851 |
| DOI | 10.1002/anie.201808926 |
| 通讯作者 | Lu, Xing(lux@hust.edu.cn) ; Gan, Liangbing(gan@pku.edu.cn) |
| 英文摘要 | An open-cage [60]fullerene was prepared through a multiple-step sequence based on peroxide-mediated cage-opening reactions. Key steps include repeated C-60-sensitized singlet-oxygen oxidation of electron-rich amino enol double bonds to form two lactone and two lactam moieties on the rim of the orifice. Single-crystal X-ray analysis shows that the 22-membered orifice has an ellipsoid shape with the major axis at 6.7 angstrom and the minor axis at 3.5 angstrom. Encapsulation of H2O2 was observed under atmospheric pressure at room temperature. Oxygen is also effectively trapped during the process. |
| WOS关键词 | MOLECULAR-HYDROGEN ; CARBON-ATOM ; C-60 ; CYANIDE |
| 资助项目 | NNSFC[21132007] ; NNSFC[21672009] ; NNSFC[51472095] ; NNSFC[51672093] ; MOST[2015CB856600] |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000447371500027 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 资助机构 | NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST ; NNSFC ; NNSFC ; MOST ; MOST |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/166928]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Lu, Xing; Gan, Liangbing |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Sch Mat Sci & Engn, 1037 Luoyu Rd, Wuhan 430074, Hubei, Peoples R China 3.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Xing,Gan, Liangbing,Li, Yanbang,et al. Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,2018,57(43):14144-14148. |
| APA | Lu, Xing,Gan, Liangbing,Li, Yanbang,Lou, Ning,Xu, Dan,&Pan, Changwang.(2018).Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2.ANGEWANDTE CHEMIE-INTERNATIONAL EDITION,57(43),14144-14148. |
| MLA | Lu, Xing,et al."Oxygen-Delivery Materials: Synthesis of an Open-Cage Fullerene Derivative Suitable for Encapsulation of H2O2 and O-2".ANGEWANDTE CHEMIE-INTERNATIONAL EDITION 57.43(2018):14144-14148. |
入库方式： OAI收割
来源：大连化学物理研究所
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