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Rhodium(III)-Catalyzed Redox-Neutral Synthesis of Isoquinolinium Salts via C-H Activation of Imines

文献类型：期刊论文

作者Zheng, Guangfan1; Li, Xingwei1,2; Tian, Miaomiao2; Fan, Xuesen2
刊名JOURNAL OF ORGANIC CHEMISTRY
出版日期2018-06-15
卷号83期号:12页码:6477-6488
ISSN号0022-3263
DOI10.1021/acs.joc.8b00758
通讯作者Li, Xingwei(xwli@dicp.ac.cn)
英文摘要Redox-neutral synthesis of isoquinolinium salts via C-H activation of presynthesized or in situ formed imines and coupling with alpha-diazo ketoesters has been realized, where a zinc salt promotes cyclization as well as provides a counteranion. Under three-component conditions, both ketone and aldehydes are viable arene sources. The coupling of imines with diazo malonates under similar conditions afforded isoquinolin-3-ones as the coupling product.
WOS关键词BOND ACTIVATION ; DIAZO-COMPOUNDS ; RH(III)-CATALYZED ANNULATION ; CATALYZED CYCLIZATION ; AROMATIC KETIMINES ; CINNOLINIUM SALTS ; ALKYNES ; HETEROCYCLES ; ACCESS ; FUNCTIONALIZATION
资助项目NSFC[21525208] ; NSFC[21472186] ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
WOS研究方向Chemistry
语种英语
WOS记录号WOS:000445712900021
出版者AMER CHEMICAL SOC
资助机构NSFC ; NSFC ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; NSFC ; NSFC ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; NSFC ; NSFC ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; NSFC ; NSFC ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences) ; Dalian Institute of Chemical Physics (Chinese Academy of Sciences)
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166960]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Li, Xingwei
作者单位1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian 116023, Peoples R China
2.Henan Normal Univ, Henan Key Lab Organ Funct Mol & Drug Innovat, Xinxiang 453007, Peoples R China
推荐引用方式
GB/T 7714		 Zheng, Guangfan,Li, Xingwei,Tian, Miaomiao,et al. Rhodium(III)-Catalyzed Redox-Neutral Synthesis of Isoquinolinium Salts via C-H Activation of Imines[J]. JOURNAL OF ORGANIC CHEMISTRY,2018,83(12):6477-6488.
APA Zheng, Guangfan,Li, Xingwei,Tian, Miaomiao,&Fan, Xuesen.(2018).Rhodium(III)-Catalyzed Redox-Neutral Synthesis of Isoquinolinium Salts via C-H Activation of Imines.JOURNAL OF ORGANIC CHEMISTRY,83(12),6477-6488.
MLA Zheng, Guangfan,et al."Rhodium(III)-Catalyzed Redox-Neutral Synthesis of Isoquinolinium Salts via C-H Activation of Imines".JOURNAL OF ORGANIC CHEMISTRY 83.12(2018):6477-6488.

入库方式： OAI收割

来源：大连化学物理研究所

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