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Chiral sensors for determining the absolute configurations of -amino acid derivatives

文献类型：期刊论文

作者Fan, Hongjun2; Chen, Zhongxiang1,3; Yang, Shiwei1,3; Bian, Guangling1,3; Song, Ling1,3
刊名ORGANIC & BIOMOLECULAR CHEMISTRY
出版日期2018-10-07
卷号16期号:37页码:6933-6939
ISSN号1477-0520
DOI10.1039/c8ob01933a
通讯作者Bian, Guangling(glb@fjirsm.ac.cn) ; Song, Ling(songling@fjirsm.ac.cn)
英文摘要A simple strategy for configurational assignments of alpha-amino acids has been developed by comparison of the proton NMR chemical shift values of the alpha hydrogens of N-phthaloyl protected alpha-amino acids in the presence of (R)-CSA 1 and (S)-CSA 1, respectively. Highly resolved NMR spectra can be obtained directly on the mixed solution of the chiral solvating agents with N-phthaloyl protected alpha-amino acids in NMR tubes, giving well distinguishable proton signals without interference which dramatically improve the accuracy of assignment and hasten the assigning procedure. The strategy is widely applicable for varied natural and non-natural amino acids.
WOS关键词ALPHA-HYDROXY ACIDS ; NMR-SPECTROSCOPY ; CARBOXYLIC-ACIDS ; SOLVATING AGENTS ; ENANTIOSELECTIVE RECOGNITION ; H-1-NMR SPECTROSCOPY ; C(SP(3))-H BONDS ; SHIFT-REAGENT ; F-19 NMR ; DISCRIMINATION
资助项目Strategic Priority Research Program of the Chinese Academy of Sciences[XDB20000000] ; DICP[DICP DMTO201404] ; Natural Science Foundation of Fujian Province, China[2018J01029] ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences
WOS研究方向Chemistry
语种英语
出版者ROYAL SOC CHEMISTRY
WOS记录号WOS:000445637600014
资助机构Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; DICP ; DICP ; Natural Science Foundation of Fujian Province, China ; Natural Science Foundation of Fujian Province, China ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; DICP ; DICP ; Natural Science Foundation of Fujian Province, China ; Natural Science Foundation of Fujian Province, China ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; DICP ; DICP ; Natural Science Foundation of Fujian Province, China ; Natural Science Foundation of Fujian Province, China ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Strategic Priority Research Program of the Chinese Academy of Sciences ; DICP ; DICP ; Natural Science Foundation of Fujian Province, China ; Natural Science Foundation of Fujian Province, China ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences ; Key Laboratory of Coal to Ethylene Glycol and Its Related Technology, the Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences
源URL[http://cas-ir.dicp.ac.cn/handle/321008/166986]  
专题大连化学物理研究所_中国科学院大连化学物理研究所
通讯作者Bian, Guangling; Song, Ling
作者单位1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China
3.Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & its Related Techno, Fuzhou 350002, Fujian, Peoples R China
推荐引用方式
GB/T 7714		 Fan, Hongjun,Chen, Zhongxiang,Yang, Shiwei,et al. Chiral sensors for determining the absolute configurations of -amino acid derivatives[J]. ORGANIC & BIOMOLECULAR CHEMISTRY,2018,16(37):6933-6939.
APA Fan, Hongjun,Chen, Zhongxiang,Yang, Shiwei,Bian, Guangling,&Song, Ling.(2018).Chiral sensors for determining the absolute configurations of -amino acid derivatives.ORGANIC & BIOMOLECULAR CHEMISTRY,16(37),6933-6939.
MLA Fan, Hongjun,et al."Chiral sensors for determining the absolute configurations of -amino acid derivatives".ORGANIC & BIOMOLECULAR CHEMISTRY 16.37(2018):6933-6939.

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来源：大连化学物理研究所

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