Bromine Doping as an Efficient Strategy to Reduce the Interfacial Defects in Hybrid Two-Dimensional/Three-Dimensional Stacking Perovskite Solar Cells
文献类型：期刊论文
| 作者 | Shi, Yantao3; Song, Xuedan3; Hao, Ce3; Liu, Junxue1; Jin, Shengye1; Feng, Yulin3; Wang, Shi3; Lv, Yanping3; Wang, Minhuan2 |
| 刊名 | ACS APPLIED MATERIALS & INTERFACES
 |
| 出版日期 | 2018-09-19 |
| 卷号 | 10期号:37页码:31755-31764 |
| 关键词 | 2D/3D stacking structure doping interfacial defect charge recombination perovskite solar cell |
| ISSN号 | 1944-8244 |
| DOI | 10.1021/acsami.8b09461 |
| 通讯作者 | Shi, Yantao(shiyantao@dlut.edu.cn) |
| 英文摘要 | Solar-to-electricity conversion efficiency, power conversion efficiency (PCE), and stability are two important aspects of perovskite solar cells (PSCs). However, both aspects are difficult to simultaneously enhance. In the recent two years, two-dimensional (2D)/three-dimensional (3D) stacking structure, designed by covering the 3D perovskite with a thin 2D perovskite capping layer, was reported to be a promising method to achieve both a higher PCE and improved stability simultaneously. However, when reducing the surface defects of 3D perovskite, the thin 2D capping layer itself may probably introduce additional interfacial defects in a 2D/3D stacking structure, which is thought to be able to trigger trap-assisted nonradiative recombination or ion migration. Thus, efforts should be paid to reduce the interfacial defects of 2D hybrid perovskite when serving as a modification layer in a 2D/3D stacking structure PSCs. Here, we demonstrate that bromine (Br) doping of the 2D perovskite capping layer is an efficient strategy to passivate interfacial defects robustly, by which the photoluminescence lifetime is enhanced notably, whereas the interfacial charge recombination is suppressed a lot. As a result, the PCE is enhanced from 18.01% (3D perovskite) to 20.07% (Br-doped 2D/3D perovskite) along with improved moisture stability. |
| WOS关键词 | PHOTOVOLTAICS ; ELECTRON ; LAYER ; CH3NH3PBI3 ; STABILITY ; FILMS |
| 资助项目 | National Natural Science Foundation of China[51402036] ; National Natural Science Foundation of China[51773025] ; International Science & Technology Cooperation Program of China[2013DFA51000] |
| WOS研究方向 | Science & Technology - Other Topics ; Materials Science |
| 语种 | 英语 |
| WOS记录号 | WOS:000445439900088 |
| 出版者 | AMER CHEMICAL SOC |
| 资助机构 | National Natural Science Foundation of China ; National Natural Science Foundation of China ; International Science & Technology Cooperation Program of China ; International Science & Technology Cooperation Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; International Science & Technology Cooperation Program of China ; International Science & Technology Cooperation Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; International Science & Technology Cooperation Program of China ; International Science & Technology Cooperation Program of China ; National Natural Science Foundation of China ; National Natural Science Foundation of China ; International Science & Technology Cooperation Program of China ; International Science & Technology Cooperation Program of China |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167050]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Shi, Yantao |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Mol React Dynam, Dalian 116023, Peoples R China 2.Dalian Univ Technol, Key Lab Mat Modificat Laser Ion & Elect Beams, Minist Educ, Sch Phys & Optoelect Technol, Dalian 116024, Peoples R China 3.Dalian Univ Technol, Sch Chem, State Key Lab Fine Chem, Dalian 116024, Peoples R China |
| 推荐引用方式 GB/T 7714 | Shi, Yantao,Song, Xuedan,Hao, Ce,et al. Bromine Doping as an Efficient Strategy to Reduce the Interfacial Defects in Hybrid Two-Dimensional/Three-Dimensional Stacking Perovskite Solar Cells[J]. ACS APPLIED MATERIALS & INTERFACES,2018,10(37):31755-31764. |
| APA | Shi, Yantao.,Song, Xuedan.,Hao, Ce.,Liu, Junxue.,Jin, Shengye.,...&Wang, Minhuan.(2018).Bromine Doping as an Efficient Strategy to Reduce the Interfacial Defects in Hybrid Two-Dimensional/Three-Dimensional Stacking Perovskite Solar Cells.ACS APPLIED MATERIALS & INTERFACES,10(37),31755-31764. |
| MLA | Shi, Yantao,et al."Bromine Doping as an Efficient Strategy to Reduce the Interfacial Defects in Hybrid Two-Dimensional/Three-Dimensional Stacking Perovskite Solar Cells".ACS APPLIED MATERIALS & INTERFACES 10.37(2018):31755-31764. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。