Structural transformation of h-BN overlayers on Pt(111) in oxidative atmospheres
文献类型：期刊论文
| 作者 | Fu, Qiang2; Meng, Caixia2,3; Li, Yifan1,2; Wu, Hao1,2; Wei, Wei1,2; Ning, Yanxiao2; Cui, Yi4; Bao, Xinhe1,2 |
| 刊名 | PHYSICAL CHEMISTRY CHEMICAL PHYSICS
 |
| 出版日期 | 2018-04-28 |
| 卷号 | 20期号:16页码:11013-11020 |
| ISSN号 | 1463-9076 |
| DOI | 10.1039/c8cp00877a |
| 文献子类 | Article |
| 英文摘要 | Interaction of hexagonal boron nitride (h-BN) with gases is of great importance for its properties and applications. In the present work, the structural changes of h-BN overlayers on Pt(111) in oxidative atmospheres including O-2 and NO2 have been investigated by using low energy electron microscopy, Auger electron spectroscopy, X-ray photoelectron spectroscopy (XPS), and near ambient pressure XPS. We find that h-BN islands can be intercalated by oxygen in 10(-6) Torr O-2 at 200 degrees C, while oxygen intercalation of full layer h-BN around 200 degrees C requires near ambient pressure O-2 (0.1 Torr) or such a strong oxidant as NO2 (10(-6) Torr). h-BN overlayers can be etched away in the gases at much high temperatures, e.g. 800 degrees C. Upon mild oxidation in O-2 or NO2 at temperatures of 400-450 degrees C, h-BN is transformed to boron oxide (BOx) overlayers, which can be converted back to h-BN by heating in NH3 at 800 degrees C. |
| WOS关键词 | HEXAGONAL BORON-NITRIDE ; ENERGY-ELECTRON MICROSCOPY ; OXYGEN INTERCALATION ; SURFACE-CHEMISTRY ; GRAPHENE OXIDE ; METAL-SURFACES ; ATOMIC OXYGEN ; NO2 ; MONOLAYER ; DECOMPOSITION |
| WOS研究方向 | Chemistry ; Physics |
| 语种 | 英语 |
| WOS记录号 | WOS:000431821800039 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167138]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Fu, Qiang |
| 作者单位 | 1.Univ Sci & Technol China, Dept Chem Phys, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100039, Peoples R China 4.Chinese Acad Sci, Suzhou Inst Nanotech & Nanobion, Vacuum Interconnected Nanotech Workstn, Suzhou 215123, Peoples R China |
| 推荐引用方式 GB/T 7714 | Fu, Qiang,Meng, Caixia,Li, Yifan,et al. Structural transformation of h-BN overlayers on Pt(111) in oxidative atmospheres[J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS,2018,20(16):11013-11020. |
| APA | Fu, Qiang.,Meng, Caixia.,Li, Yifan.,Wu, Hao.,Wei, Wei.,...&Bao, Xinhe.(2018).Structural transformation of h-BN overlayers on Pt(111) in oxidative atmospheres.PHYSICAL CHEMISTRY CHEMICAL PHYSICS,20(16),11013-11020. |
| MLA | Fu, Qiang,et al."Structural transformation of h-BN overlayers on Pt(111) in oxidative atmospheres".PHYSICAL CHEMISTRY CHEMICAL PHYSICS 20.16(2018):11013-11020. |
入库方式： OAI收割
来源：大连化学物理研究所
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