Single-atom catalysis: Bridging the homo- and heterogeneous catalysis
文献类型：期刊论文
| 作者 | Lang, Rui1; Chen, Fang1; Jiang, Xunzhu1,2; Zhang, Leilei1; Qiao, Botao1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 39期号:5页码:893-898 |
| 关键词 | Single-atom Catalysis Heterogenization Of Homogeneous Catalysts Hydroformation Hydrosilylation Activation Of C-h Bonds |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/51872-2067(18)63047-5 |
| 文献子类 | Review |
| 英文摘要 | Single-atom catalysis, the catalysis by single-atom catalysts (SACs), has attracted considerable attention in recent years as a new frontier in the heterogeneous catalysis field. SACs have the advantages of both homogeneous catalysts (isolated active sites) and heterogeneous catalysts (stable and easy to separate), and are thus predicted to be able to bridge the homo- and heterogeneous catalysis. This prediction was first experimentally demonstrated in 2016. In this mini-review, we summarize the few homogeneous catalysis progresses reported recently where SACs have exhibited promising application: a) Rh/ZnO and Rh/CoO SAC have been used successfully in hydroformylation of olefin of which the activity are comparable to the homogeneous Wilkinson's catalyst; b) a Pt/Al2O3 SAC has shown excellent performance in hydrosilylation reaction; and c) M-N-C SACs (M = Fe, Co etc.) have been applied in the activation of C-H bonds. All of these examples suggest that fabrication of suitable SACs could provide a new avenue for the heterogenization of homogeneous catalysts. These pioneering works shed new light on the recognition of single-atom catalysis in bridging the homo- and heterogeneous catalysis. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | N-C CATALYST ; SELECTIVE OXIDATION ; HYDROFORMYLATION ; PERFORMANCE |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000431834500001 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167140]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Qiao, Botao |
| 作者单位 | 1.Chinese Acad Sci, State Key Lab Catalysis, Dalian Inst Chem Phys, Dalian 116023, Liaoning, Peoples R China 2.Dalian Univ Technol, Sch Chem, Dalian 116024, Liaoning, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lang, Rui,Chen, Fang,Jiang, Xunzhu,et al. Single-atom catalysis: Bridging the homo- and heterogeneous catalysis[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(5):893-898. |
| APA | Lang, Rui,Chen, Fang,Jiang, Xunzhu,Zhang, Leilei,&Qiao, Botao.(2018).Single-atom catalysis: Bridging the homo- and heterogeneous catalysis.CHINESE JOURNAL OF CATALYSIS,39(5),893-898. |
| MLA | Lang, Rui,et al."Single-atom catalysis: Bridging the homo- and heterogeneous catalysis".CHINESE JOURNAL OF CATALYSIS 39.5(2018):893-898. |
入库方式： OAI收割
来源：大连化学物理研究所
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