La and Cr Co-doped SrTiO3 as an H-2 evolution photocatalyst for construction of a Z-scheme overall water splitting system
文献类型：期刊论文
| 作者 | Li, Mingrun1; Jia, Yushuai1,2; Li, Can1; Zhao, Dan1; Han, Hongxian1 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2018-03-01 |
| 卷号 | 39期号:3页码:421-430 |
| 关键词 | Strontium Titanate Photocatalysis Water Splitting Z-scheme Hydrogen Evolution |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(18)63027-X |
| 文献子类 | Article |
| 英文摘要 | The photocatalytic activity of a semiconductor-based photocatalyst largely depends on the semiconductor's intrinsic crystal and electronic properties. We have prepared two types of La and Cr co-doped SrTiO3 photocatalysts (SrTiO3(La,Cr)) using the polymerized complex method (PCM) and sol-gel hydrothermal method (SHM). Under lambda > 420-nm visible light irradiation, only the Pt-loaded SrTiO3(La,Cr) prepared by the SHM showed efficient photocatalytic activities for both H-2 evolution in the presence of an I- sacrificial reagent and for Z-scheme overall water splitting when it was coupled with the Pt-loaded WO3 in the presence I- of and IO(3)(-)as the shuttle redox mediator. The superior photocatalytic activity of SrTiO3(La,Cr) prepared by the SHM has been ascribed to its more negative conduction-band position, higher carrier concentration, and higher carrier mobility, demonstrating that the design and synthesis of an H-2-evolution photocatalyst with appropriate electronic properties is crucial for achieving Z-scheme overall water splitting. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | VISIBLE-LIGHT IRRADIATION ; SHUTTLE REDOX MEDIATOR ; DIFFERENT SEMICONDUCTOR PHOTOCATALYSTS ; HYDROGEN-PRODUCTION ; 2-STEP PHOTOEXCITATION ; ELECTRON MEDIATOR ; PHASE JUNCTION ; GENERATION ; TIO2 ; O-2 |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000430989100009 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167152]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Can; Han, Hongxian |
| 作者单位 | 1.Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, State Key Lab Catalysis, Dalian 116023, Liaoning, Peoples R China 2.Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Jiangxi, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Mingrun,Jia, Yushuai,Li, Can,et al. La and Cr Co-doped SrTiO3 as an H-2 evolution photocatalyst for construction of a Z-scheme overall water splitting system[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(3):421-430. |
| APA | Li, Mingrun,Jia, Yushuai,Li, Can,Zhao, Dan,&Han, Hongxian.(2018).La and Cr Co-doped SrTiO3 as an H-2 evolution photocatalyst for construction of a Z-scheme overall water splitting system.CHINESE JOURNAL OF CATALYSIS,39(3),421-430. |
| MLA | Li, Mingrun,et al."La and Cr Co-doped SrTiO3 as an H-2 evolution photocatalyst for construction of a Z-scheme overall water splitting system".CHINESE JOURNAL OF CATALYSIS 39.3(2018):421-430. |
入库方式： OAI收割
来源：大连化学物理研究所
浏览0
下载0
收藏0
其他版本
除非特别说明，本系统中所有内容都受版权保护，并保留所有权利。