Effective removal of the protective ligands from Au nanoclusters by ambient pressure nonthermal plasma treatment for CO oxidation
文献类型：期刊论文
| 作者 | Tan, Yuan1,2; Liu, Hua1,2; Liu, Xiao Yan2; Wang, Aiqin2; Liu, Changjun3; Zhang, Tao1,2 |
| 刊名 | CHINESE JOURNAL OF CATALYSIS
 |
| 出版日期 | 2018-05-01 |
| 卷号 | 39期号:5页码:929-936 |
| 关键词 | Gold Cluster Plasma Supported Gold Catalyst Protective Ligand Carbon Monoxide Oxidation |
| ISSN号 | 0253-9837 |
| DOI | 10.1016/S1872-2067(18)63018-9 |
| 文献子类 | Article |
| 英文摘要 | We used a dielectric barrier discharge (DBD) plasma technique to eliminate the protective ligand of ZnAl-hydrotalcite-supported gold nanoclusters. We used X-ray powder diffraction, ultraviolet-visible spectrophotometry, thermogravimetric analysis, and high angle annular dark-field-scanning transmission electron microscopy characterization to show that the samples pretreated with/without DBD-plasma displayed different performances in CO oxidation. The enhanced activity was obtained on the plasma-treated samples, implying that the protective ligand was effectively removed via the plasma technique. The crystal structure of the plasma-treated samples changed markedly, suggesting that the plasma treatment could not only break the chemical bond between the gold and the protective agent but could also decompose the interlayer ions over the hydrotalcite support. The particle sizes of the gold after DBD-plasma treatment implied that it was a good way to control the size of the gold nanoparticles under mild conditions. (C) 2018, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. |
| WOS关键词 | LOW-TEMPERATURE OXIDATION ; GOLD CATALYSTS ; AU-25 NANOCLUSTERS ; AU/TIO2 CATALYSTS ; THIOLATE LIGANDS ; ATOMIC PRECISION ; CARBON-MONOXIDE ; NANOPARTICLES ; SIZE ; HYDROGENATION |
| WOS研究方向 | Chemistry ; Engineering |
| 语种 | 英语 |
| WOS记录号 | WOS:000431834500006 |
| 出版者 | SCIENCE PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167174]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Xiao Yan |
| 作者单位 | 1.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 2.Chinese Acad Sci, State Key Lab Catalysis, iChEM Collaborat Innovat Ctr Chem Energy Mat, Dalian Inst Chem Phys,Gold Catalysis Res Ctr, Dalian 116023, Liaoning, Peoples R China 3.Tianjin Univ, Sch Chem Engn & Technol, Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China |
| 推荐引用方式 GB/T 7714 | Tan, Yuan,Liu, Hua,Liu, Xiao Yan,et al. Effective removal of the protective ligands from Au nanoclusters by ambient pressure nonthermal plasma treatment for CO oxidation[J]. CHINESE JOURNAL OF CATALYSIS,2018,39(5):929-936. |
| APA | Tan, Yuan,Liu, Hua,Liu, Xiao Yan,Wang, Aiqin,Liu, Changjun,&Zhang, Tao.(2018).Effective removal of the protective ligands from Au nanoclusters by ambient pressure nonthermal plasma treatment for CO oxidation.CHINESE JOURNAL OF CATALYSIS,39(5),929-936. |
| MLA | Tan, Yuan,et al."Effective removal of the protective ligands from Au nanoclusters by ambient pressure nonthermal plasma treatment for CO oxidation".CHINESE JOURNAL OF CATALYSIS 39.5(2018):929-936. |
入库方式： OAI收割
来源：大连化学物理研究所
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