Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor
文献类型：期刊论文
| 作者 | Zhang, Tao3; Liu, Fei3; Liu, Qiaoyun3,4; Xu, Jinming3; Li, Lei5; Cui, Yi-Tao2; Lang, Rui3; Li, Lin3; Su, Yang3; Miao, Shu3 |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2018-04-21 |
| 卷号 | 20期号:8页码:1770-1776 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c8gc00039e |
| 文献子类 | Article |
| 英文摘要 | The synthesis of bio-based linear diols is the subject of many research studies. However, one of the main obstacles in industrial development is the difficulty in controlling product selectivity. Here, we report the catalytic conversion of furfural to 1,4-pentanediol (PD) in the presence of Ru supported on an ordered mesoporous carbon (CMK-3) under pressure of H-2 and CO2 in water. In contrast to previous catalytic pathways, this work is distinct in that it yields 1,4-PD as an exclusive product, instead of a mixture of 1,2-and 1,5-PD as usual. Under optimized conditions, 1,4-PD was obtained in 90% yield, and in a one-pot reaction, directly from furfural. We disclose that the conversion of furfural to 1,4-PD followed an unusual catalytic route. It implies a bifunctional catalytic pathway based on sequential catalytic hydrogenation reactions and an acid-catalyzed Piancatelli's rearrangement. |
| WOS关键词 | LEVULINIC ACID ; GAMMA-VALEROLACTONE ; ETHYLENE-GLYCOL ; CHEMOSELECTIVE HYDROGENOLYSIS ; HYDROGENATION ; CHEMICALS ; BIOMASS ; OXIDATION ; CELLULOSE ; PLATFORM |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000430708900009 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167184]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Qiao, Botao; Jerome, Francois; Wang, Aiqin |
| 作者单位 | 1.Univ Poitiers, CNRS, Inst Chim Milieux & Mat Poitiers, F-86073 Poitiers, France 2.Univ Tokyo, Inst Solid State Phys, Tokyo, Hyogo 6795198, Japan 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Univ Hyogo, Synchrotron Radiat Nanotechnol Ctr, Kobe, Hyogo 6795165, Japan |
| 推荐引用方式 GB/T 7714 | Zhang, Tao,Liu, Fei,Liu, Qiaoyun,et al. Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor[J]. GREEN CHEMISTRY,2018,20(8):1770-1776. |
| APA | Zhang, Tao.,Liu, Fei.,Liu, Qiaoyun.,Xu, Jinming.,Li, Lei.,...&Wang, Aiqin.(2018).Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor.GREEN CHEMISTRY,20(8),1770-1776. |
| MLA | Zhang, Tao,et al."Catalytic cascade conversion of furfural to 1,4-pentanediol in a single reactor".GREEN CHEMISTRY 20.8(2018):1770-1776. |
入库方式： OAI收割
来源：大连化学物理研究所
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