Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand
文献类型：期刊论文
| 作者 | Lu, Sheng-Mei; Wang, Zhijun; Wang, Jijie; Li, Jun; Li, Can |
| 刊名 | GREEN CHEMISTRY
 |
| 出版日期 | 2018-04-21 |
| 卷号 | 20期号:8页码:1835-1840 |
| ISSN号 | 1463-9262 |
| DOI | 10.1039/c8gc00495a |
| 文献子类 | Article |
| 英文摘要 | A new iridium catalyst bearing a dioxime derived ligand has been developed for aqueous formic acid (FA) dehydrogenation. This catalyst features high stability and high efficiency for dehydrogenation of FA in aqueous solution without any additives. With the in situ formed catalysts, TONs of up to 3900000 (average rate: 65000 h(-1)) at 90 degrees C were achieved. At 70 degrees C, an even higher TON of 5020000 was obtained, which is the highest TON ever reported. More interestingly, this catalyst can also give a TON of 400000 and an average rate of 1053 h(-1) even at room temperature. Electron-rich amine substituents and the dioxime structure of the ligand are beneficial to the high stability and high efficiency of the catalyst. |
| WOS关键词 | IR COMPLEXES ; SELECTIVE DEHYDROGENATION ; REVERSIBLE HYDROGENATION ; HOMOGENEOUS CATALYSTS ; RUTHENIUM CATALYST ; AQUEOUS-SOLUTION ; CARBON-DIOXIDE ; STORAGE ; WATER ; CO2 |
| WOS研究方向 | Chemistry ; Science & Technology - Other Topics |
| 语种 | 英语 |
| WOS记录号 | WOS:000430708900016 |
| 出版者 | ROYAL SOC CHEMISTRY |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167190]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Li, Can |
| 作者单位 | Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, 457 Zhongshan Rd, Dalian 116023, Peoples R China |
| 推荐引用方式 GB/T 7714 | Lu, Sheng-Mei,Wang, Zhijun,Wang, Jijie,et al. Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand[J]. GREEN CHEMISTRY,2018,20(8):1835-1840. |
| APA | Lu, Sheng-Mei,Wang, Zhijun,Wang, Jijie,Li, Jun,&Li, Can.(2018).Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand.GREEN CHEMISTRY,20(8),1835-1840. |
| MLA | Lu, Sheng-Mei,et al."Hydrogen generation from formic acid decomposition on a highly efficient iridium catalyst bearing a diaminoglyoxime ligand".GREEN CHEMISTRY 20.8(2018):1835-1840. |
入库方式： OAI收割
来源：大连化学物理研究所
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