Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation
文献类型：期刊论文
| 作者 | Li, Xianjiang; Chang, Cuilan; Wang, Xin; Bai, Yu; Liu, Huwei |
| 刊名 | ELECTROPHORESIS
 |
| 出版日期 | 2014-10-01 |
| 卷号 | 35期号:19页码:2733-2743 |
| 关键词 | Chiral Separation Chiral Stationary Phase Enantioselective Adsorption Metal-organic Frameworks |
| ISSN号 | 0173-0835 |
| DOI | 10.1002/elps.201400079 |
| 文献子类 | Review |
| 英文摘要 | Chiral separation is of great importance for drug development, pharmacology, and biology. Chiral metal-organic frameworks (MOFs) is a new class of porous solid materials with high surface area, large pore size, high chemical stability, uniformly structured cavities, and the availability of modification. The excellent properties of MOFs have attracted intense interest to explore their performance and mechanism in chiral separation. This review summarizes three synthetic strategies of chiral MOFs and their applications in enantioselective adsorption and chromatographic separation. All the experimental and molecular simulation results demonstrated that high enantioselectivity was strongly correlated with a close match between the size of the pore and chiral molecules. |
| WOS关键词 | PERFORMANCE LIQUID-CHROMATOGRAPHY ; HIGHLY SELECTIVE SEPARATION ; INTRINSIC CHIRAL TOPOLOGY ; ACHIRAL BUILDING-BLOCKS ; STATIONARY-PHASE ; COORDINATION POLYMERS ; CAPILLARY ELECTROCHROMATOGRAPHY ; ABSOLUTE HELICITY ; POROUS SOLIDS ; RESOLUTION |
| WOS研究方向 | Biochemistry & Molecular Biology ; Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000342910300005 |
| 出版者 | WILEY-BLACKWELL |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167290]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Liu, Huwei |
| 作者单位 | Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Inst Analyt Chem,Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Xianjiang,Chang, Cuilan,Wang, Xin,et al. Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation[J]. ELECTROPHORESIS,2014,35(19):2733-2743. |
| APA | Li, Xianjiang,Chang, Cuilan,Wang, Xin,Bai, Yu,&Liu, Huwei.(2014).Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation.ELECTROPHORESIS,35(19),2733-2743. |
| MLA | Li, Xianjiang,et al."Applications of homochiral metal-organic frameworks in enantioselective adsorption and chromatography separation".ELECTROPHORESIS 35.19(2014):2733-2743. |
入库方式： OAI收割
来源：大连化学物理研究所
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