Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes
文献类型：期刊论文
| 作者 | Li, Yanbang2; Gan, Liangbing1,2 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-09-19 |
| 卷号 | 79期号:18页码:8912-8916 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo5015867 |
| 文献子类 | Article |
| 英文摘要 | Secondary amines are well-known to add to [60]fullerene to form the tetraamino epoxy adduct C-60(O)(NR1R2)(4) under both photolysis and thermal conditions in the presence of oxygen. We have now found that pentaamino hydroxyl adduct C-60(OH)(NR1R2)(5) and hexaamino adduct C-60(NR1R2)(6) can be formed as the major products in the dark in the presence of oxygen. Key steps of the reaction mechanism probably involve repeated oxygen oxidation of the radical ion pair between fullerene and amines. |
| WOS关键词 | VIVO GENE DELIVERY ; ELECTRON-TRANSFER ; TERTIARY-AMINES ; FUNCTIONALIZED FULLERENES ; DERIVATIVES ; FACILE ; OXYGEN ; PHOTOADDITION ; PIPERAZINE ; OXIDANT |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000342121100048 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167316]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gan, Liangbing |
| 作者单位 | 1.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China 2.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Li, Yanbang,Gan, Liangbing. Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(18):8912-8916. |
| APA | Li, Yanbang,&Gan, Liangbing.(2014).Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes.JOURNAL OF ORGANIC CHEMISTRY,79(18),8912-8916. |
| MLA | Li, Yanbang,et al."Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes".JOURNAL OF ORGANIC CHEMISTRY 79.18(2014):8912-8916. |
入库方式： OAI收割
来源：大连化学物理研究所
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