Using the Type II Cycloisomerization Reaction of 1,6-Enynes as a Mechanistic Probe to Identify the Real Catalytic Species of GaX3 and InX3
文献类型：期刊论文
| 作者 | Zhuo, Lian-Gang; Shi, Yao-Cheng; Yu, Zhi-Xiang |
| 刊名 | ASIAN JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-08-01 |
| 卷号 | 3期号:8页码:842-846 |
| 关键词 | Cycloisomerization Dienes Gallium Indium 1 6-enynes |
| ISSN号 | 2193-5807 |
| DOI | 10.1002/ajoc.201402070 |
| 文献子类 | Article |
| 英文摘要 | Previously, we found that InCl2+ is the real catalytic species in InCl3-catalyzed type II cycloisomerization of 1,6-enynes for generating nonconjugated dienes. We further used this cycloisomerization reaction as a mechanistic probe to study whether GaCl3, GaBr3, InBr3, InI3 also have GaCl2+, GaBr2+, InBr2+, and InI2+ as the real catalytic species. Experimental and computational results from the mechanistic probe reaction here support that the real catalytic species are positively charged GaCl2+, GaBr2+, InBr2+, and InI2+. |
| WOS关键词 | SKELETAL REORGANIZATION ; CYCLOADDITION REACTIONS ; ORGANIC-SYNTHESIS ; LEWIS-ACIDS ; COMPLEXES ; ENYNES ; GACL3 ; REARRANGEMENTS ; DISCOVERY ; DENSITY |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000340558500003 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167318]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Yu, Zhi-Xiang |
| 作者单位 | Peking Univ, Key Lab Bioorgan Chem & Mol Engn, Coll Chem, Beijing Natl Lab Mol Sci, Beijing 100871, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhuo, Lian-Gang,Shi, Yao-Cheng,Yu, Zhi-Xiang. Using the Type II Cycloisomerization Reaction of 1,6-Enynes as a Mechanistic Probe to Identify the Real Catalytic Species of GaX3 and InX3[J]. ASIAN JOURNAL OF ORGANIC CHEMISTRY,2014,3(8):842-846. |
| APA | Zhuo, Lian-Gang,Shi, Yao-Cheng,&Yu, Zhi-Xiang.(2014).Using the Type II Cycloisomerization Reaction of 1,6-Enynes as a Mechanistic Probe to Identify the Real Catalytic Species of GaX3 and InX3.ASIAN JOURNAL OF ORGANIC CHEMISTRY,3(8),842-846. |
| MLA | Zhuo, Lian-Gang,et al."Using the Type II Cycloisomerization Reaction of 1,6-Enynes as a Mechanistic Probe to Identify the Real Catalytic Species of GaX3 and InX3".ASIAN JOURNAL OF ORGANIC CHEMISTRY 3.8(2014):842-846. |
入库方式： OAI收割
来源：大连化学物理研究所
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