Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane
文献类型：期刊论文
| 作者 | Jia, Zhenshan1; Liang, Sisi1; Xu, Liang1; Gan, Liangbing1,2 |
| 刊名 | JOURNAL OF ORGANIC CHEMISTRY
 |
| 出版日期 | 2014-06-20 |
| 卷号 | 79期号:12页码:5794-5798 |
| ISSN号 | 0022-3263 |
| DOI | 10.1021/jo5009228 |
| 文献子类 | Article |
| 英文摘要 | Unlike the extensively studied perfluoroalkyl fullerene adducts, perfluorophenyl fullerene adducts are quite difficult to prepare by known methods. Trispentafluorophenylborane was found to react with fullerene epoxide to form the 1,2-perfluorophenylfullerenol. The method can be applied to both the simple epoxide C-60(O) and fullerene multiadducts containing an epoxide moiety. Single crystal X-ray structure analysis confirmed the addition of the pentafluorophenyl group. |
| WOS关键词 | NUCLEOPHILIC-SUBSTITUTION ; VICINAL FULLERENDIOL ; FLUOROALKYL GROUP ; DERIVATIVES ; BUCKMINSTERFULLERENE ; OXIDATION ; TRIS(PENTAFLUOROPHENYL)BORON ; B(C6F5)(3) ; ALCOHOLS ; ETHERS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000337871100042 |
| 出版者 | AMER CHEMICAL SOC |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167360]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gan, Liangbing |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Minist Educ,Coll Chem & Mol Engn, Beijing 100871, Peoples R China 2.Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Jia, Zhenshan,Liang, Sisi,Xu, Liang,et al. Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane[J]. JOURNAL OF ORGANIC CHEMISTRY,2014,79(12):5794-5798. |
| APA | Jia, Zhenshan,Liang, Sisi,Xu, Liang,&Gan, Liangbing.(2014).Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane.JOURNAL OF ORGANIC CHEMISTRY,79(12),5794-5798. |
| MLA | Jia, Zhenshan,et al."Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane".JOURNAL OF ORGANIC CHEMISTRY 79.12(2014):5794-5798. |
入库方式： OAI收割
来源：大连化学物理研究所
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