Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds: Towards the Synthesis of Open-Cage Fulleroid C55O5
文献类型：期刊论文
| 作者 | Gan, Liangbing1,2 |
| 刊名 | CHEMICAL RECORD
 |
| 出版日期 | 2015-02-01 |
| 卷号 | 15期号:1页码:189-198 |
| 关键词 | Cage Compounds Fullerenes Molecular Containers Peroxides Radical Reactions |
| ISSN号 | 1527-8999 |
| DOI | 10.1002/tcr.201402057 |
| 文献子类 | Article |
| 英文摘要 | Replacement of a pentagon in [60]fullerene with five oxygen atoms yields the open-cage compound C55O5 with five carbonyl groups on the rim of the orifice. Our attempts to synthesize such a target molecule starting from C-60 have led us to prepare the fullerene-mixed peroxides such as C-60(OO-t-Bu)(6) with all the peroxo addends surrounding the same pentagon. Further investigations of the peroxide chemistry have generated various open-cage fullerene derivatives, including the carbon monoxide encapsulated endohedral compound CO@C59O6. This Personal Account mainly discusses peroxide-based processes resulting in selective cleavage of the fullerene skeleton bonds. |
| WOS关键词 | ISOMERICALLY PURE FULLERENOLS ; X-RAY STRUCTURES ; MOLECULAR-HYDROGEN ; MIXED PEROXIDES ; VICINAL FULLERENDIOL ; MILD CONDITIONS ; SINGLET OXYGEN ; CARBON-ATOM ; C-60 ; DERIVATIVES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000350061300013 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167368]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Gan, Liangbing |
| 作者单位 | 1.Peking Univ, Beijing Natl Lab Mol Sci, Key Lab Bioorgan Chem & Mol Engn, Coll Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China 2.Chinese Acad Sci, State Key Lab Organometall Chem, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China |
| 推荐引用方式 GB/T 7714 | Gan, Liangbing. Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds: Towards the Synthesis of Open-Cage Fulleroid C55O5[J]. CHEMICAL RECORD,2015,15(1):189-198. |
| APA | Gan, Liangbing.(2015).Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds: Towards the Synthesis of Open-Cage Fulleroid C55O5.CHEMICAL RECORD,15(1),189-198. |
| MLA | Gan, Liangbing."Peroxide-Mediated Selective Cleavage of [60]Fullerene Skeleton Bonds: Towards the Synthesis of Open-Cage Fulleroid C55O5".CHEMICAL RECORD 15.1(2015):189-198. |
入库方式： OAI收割
来源：大连化学物理研究所
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