The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/C-H Activation Reactivity
文献类型：期刊论文
| 作者 | Zhang, Wen-Xiong1,2; Xu, Ling1; Wang, Yu-Chen1; Wei, Junnian1; Wang, Yang1; Wang, Zitao1; Xi, Zhenfeng1 |
| 刊名 | CHEMISTRY-A EUROPEAN JOURNAL
 |
| 出版日期 | 2015-04-27 |
| 卷号 | 21期号:18页码:6686-6689 |
| 关键词 | Insertion Reactions Metallacyclopentadienes Rare-earth Metals 1 4-dilithio-1 3-butadienes |
| ISSN号 | 0947-6539 |
| DOI | 10.1002/chem.201500387 |
| 文献子类 | Article |
| 英文摘要 | The first well-defined lutetacyclopentadienes are synthesised from pentamethylcyclopentadienyl lithium (Cp*Li), 1,4-dilithio-1,3-butadienes, and LuCl3. The lutetacyclopentadiene shows excellent reactivity towards some small molecules, such as pivalaldehyde, Se, carbon dioxide, and isonitrile to efficiently construct 3-, 5-, 7-, 8-, and 9-membered rare-earth metallacycles. Both monoinsertion and double-insertion of two Lu-C-sp2 bonds are observed. Specially, the reaction between lutetacyclopentadiene and isonitrile afforded [3,5,5]-fused metallacycles. The distinguished reactivity can be attributed to the highly ionic character and the cooperative reactivity of two Lu-C-sp2 bonds. |
| WOS关键词 | EARTH-METAL COMPLEXES ; MAIN-GROUP ELEMENTS ; ORGANOMETALLIC CHEMISTRY ; MOLECULAR-STRUCTURE ; TISHCHENKO REACTION ; DIFFERENT ALKYNES ; CARBON-DIOXIDE ; LIGANDS ; SCANDIUM ; BEARING |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:000353351300006 |
| 出版者 | WILEY-V C H VERLAG GMBH |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167376]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Zhang, Wen-Xiong |
| 作者单位 | 1.Peking Univ, Coll Chem, Key Lab Bioorgan Chem & Mol Engn, BNLMS,Minist Educ, Beijing 100871, Peoples R China 2.Nankai Univ, State Key Lab Elementoorgan Chem, Tianjin 300071, Peoples R China |
| 推荐引用方式 GB/T 7714 | Zhang, Wen-Xiong,Xu, Ling,Wang, Yu-Chen,et al. The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/C-H Activation Reactivity[J]. CHEMISTRY-A EUROPEAN JOURNAL,2015,21(18):6686-6689. |
| APA | Zhang, Wen-Xiong.,Xu, Ling.,Wang, Yu-Chen.,Wei, Junnian.,Wang, Yang.,...&Xi, Zhenfeng.(2015).The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/C-H Activation Reactivity.CHEMISTRY-A EUROPEAN JOURNAL,21(18),6686-6689. |
| MLA | Zhang, Wen-Xiong,et al."The First Lutetacyclopentadienes: Synthesis, Structure, and Diversified Insertion/C-H Activation Reactivity".CHEMISTRY-A EUROPEAN JOURNAL 21.18(2015):6686-6689. |
入库方式： OAI收割
来源：大连化学物理研究所
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