SURFACE COORDINATE GEOMETRY OF IRON CATALYSTS - HYDROGENATION OF CO2 OVER FE/ZRO2 PREPARED BY A NOVEL METHOD
文献类型：期刊论文
| 作者 | SUO, ZH; KOU, Y; NIU, JZ; ZHANG, WZ; WANG, HL |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 1995 |
| 卷号 | 35期号:3-4页码:271-277 |
| 关键词 | Iron Catalyst Zirconia Hydrogenation Of Co2 Mossbauer Exafs |
| ISSN号 | 1011-372X |
| 文献子类 | Article |
| 英文摘要 | Zirconia-supported iron oxide catalyst has been designed following the approach to the Fe/TiO2 catalyst. The catalyst prepared by reducing the precursor obtained from incipient wetness impregnation in H-2 at the proper temperature exhibits good activity (CO2 conversion > 20%) and selectivity (68%) in the selective synthesis of hydrocarbons (C-2-C-5) from CO2 and H-2 The catalytic activity has been found to vary with iron weight loadings in a ''two maxima'' fashion and is also affected by reduction temperature. Mossbauer and EXAFS analyses suggest that the active phases are coordinatively unsaturated ferric cations and alpha-Fe. No ferrous cations are observed. A good geometric arrangement for the two phases on the catalyst is thought to give the highest catalytic activity. |
| WOS关键词 | SUPPORTED METAL-OXIDES ; ALUMINA ; EXAFS |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:A1995TH73400008 |
| 出版者 | BALTZER SCI PUBL BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167540]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | KOU, Y |
| 作者单位 | CHINESE ACAD SCI,DALIAN INST CHEM PHYS,STATE KEY LAB CATALYSIS,DALIAN 116023,PEOPLES R CHINA |
| 推荐引用方式 GB/T 7714 | SUO, ZH,KOU, Y,NIU, JZ,et al. SURFACE COORDINATE GEOMETRY OF IRON CATALYSTS - HYDROGENATION OF CO2 OVER FE/ZRO2 PREPARED BY A NOVEL METHOD[J]. CATALYSIS LETTERS,1995,35(3-4):271-277. |
| APA | SUO, ZH,KOU, Y,NIU, JZ,ZHANG, WZ,&WANG, HL.(1995).SURFACE COORDINATE GEOMETRY OF IRON CATALYSTS - HYDROGENATION OF CO2 OVER FE/ZRO2 PREPARED BY A NOVEL METHOD.CATALYSIS LETTERS,35(3-4),271-277. |
| MLA | SUO, ZH,et al."SURFACE COORDINATE GEOMETRY OF IRON CATALYSTS - HYDROGENATION OF CO2 OVER FE/ZRO2 PREPARED BY A NOVEL METHOD".CATALYSIS LETTERS 35.3-4(1995):271-277. |
入库方式： OAI收割
来源：大连化学物理研究所
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