CARBONYLATION OF ALLYL HALIDES CATALYZED BY POLYMER-SUPPORTED PALLADIUM CATALYSTS UNDER ATMOSPHERIC-PRESSURE
文献类型：期刊论文
| 作者 | GAO, HR; XU, Y; LIAO, SJ; YU, DR |
| 刊名 | REACTIVE POLYMERS
 |
| 出版日期 | 1994-10-01 |
| 卷号 | 23期号:2-3页码:113-118 |
| 关键词 | Polymer-supported Palladium Catalysts Carbonylation Allyl Halides |
| ISSN号 | 0923-1137 |
| 文献子类 | Article |
| 英文摘要 | Palladium catalysts supported on polymers, such as poly(N-vinyl-2-pyrrolidone) (PVP), polyacrylamide (PAA), modified poly(2,6-dimethyl-1,4-phenylene oxide) (PPO) and polysulfone (PSF), were used to catalyze the carbonylation of allyl halides to form butenoic acid under mild conditions (40 degrees C, 0.1 MPa). These polymer-supported palladium catalysts exhibit very high activity and stability towards the carbonylation of allyl halides. The turnover frequencies (TOF, mol CO/mol Pd min(-1)) of PVP-Pd are up to 21 and 40 for the carbonylation of allylchloride and allylbromide, respectively, in two-phase (aqueous NaOH-benzene) medium. |
| WOS关键词 | HYDROGENATION ; COMPLEXES ; ACIDS |
| WOS研究方向 | Chemistry ; Engineering ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:A1994PN94500009 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/167844]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | CHINESE ACAD SCI,DALIAN INST CHEM PHYS,DALIAN 116023,PEOPLES R CHINA |
| 推荐引用方式 GB/T 7714 | GAO, HR,XU, Y,LIAO, SJ,et al. CARBONYLATION OF ALLYL HALIDES CATALYZED BY POLYMER-SUPPORTED PALLADIUM CATALYSTS UNDER ATMOSPHERIC-PRESSURE[J]. REACTIVE POLYMERS,1994,23(2-3):113-118. |
| APA | GAO, HR,XU, Y,LIAO, SJ,&YU, DR.(1994).CARBONYLATION OF ALLYL HALIDES CATALYZED BY POLYMER-SUPPORTED PALLADIUM CATALYSTS UNDER ATMOSPHERIC-PRESSURE.REACTIVE POLYMERS,23(2-3),113-118. |
| MLA | GAO, HR,et al."CARBONYLATION OF ALLYL HALIDES CATALYZED BY POLYMER-SUPPORTED PALLADIUM CATALYSTS UNDER ATMOSPHERIC-PRESSURE".REACTIVE POLYMERS 23.2-3(1994):113-118. |
入库方式： OAI收割
来源：大连化学物理研究所
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