Highly active polymer-alumina dually supported palladium catalysts for the carbonylation of allyl halides under atmospheric pressure
文献类型:期刊论文
作者 | Gao, HR; Xu, Y; Liao, SJ; Liu, J; Hong, H |
刊名 | CATALYSIS LETTERS
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出版日期 | 1996 |
卷号 | 40期号:3-4页码:163-166 |
关键词 | Alumina Supported Palladium Catalysts Carbonylation Allyl Halides |
ISSN号 | 1011-372X |
文献子类 | Article |
英文摘要 | Polymer-alumina dually supported palladium catalysts (PVP-Pd/Al2O3, PVP = poly(N-vinyl-2-pyrrolidone); PPPO-Pd/Al2O3, PPPO = phosphinated poly(phenylene oxide)) were used to catalyze the carbonylation of allyl halides to form butenoic acid under the mild conditions of 40 degrees C and 0.1 MPa. These catalysts exhibit high activity and stability towards the carbonylation of allyl halides. The maximum turnovers (mol CO/mol Pd) of PPPO-Pd/Al2O3 are up to 8.2 x 10(5) and 4.6 x 10(5) for the carbonylation of allyl bromide and allyl chloride respectively in an aqueous NaOH/benzene medium. |
WOS关键词 | SODIUM-HYDROXIDE ; HYDROGENATION ; COMPLEXES ; ACIDS |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:A1996VE92300006 |
出版者 | BALTZER SCI PUBL BV |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168030] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
通讯作者 | Gao, HR |
推荐引用方式 GB/T 7714 | Gao, HR,Xu, Y,Liao, SJ,et al. Highly active polymer-alumina dually supported palladium catalysts for the carbonylation of allyl halides under atmospheric pressure[J]. CATALYSIS LETTERS,1996,40(3-4):163-166. |
APA | Gao, HR,Xu, Y,Liao, SJ,Liu, J,&Hong, H.(1996).Highly active polymer-alumina dually supported palladium catalysts for the carbonylation of allyl halides under atmospheric pressure.CATALYSIS LETTERS,40(3-4),163-166. |
MLA | Gao, HR,et al."Highly active polymer-alumina dually supported palladium catalysts for the carbonylation of allyl halides under atmospheric pressure".CATALYSIS LETTERS 40.3-4(1996):163-166. |
入库方式: OAI收割
来源:大连化学物理研究所
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