Synthesis and hydrodesulfurization (HDS) and hydrogenation (HYD) activity of dimolybdenum nitride
文献类型:期刊论文
作者 | Zhang, YJ; Wei, ZB; Yan, WH; Ying, PL; Ji, CX; Li, XS; Zhou, ZH; Sun, XP; Xin, Q |
刊名 | CATALYSIS TODAY
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出版日期 | 1996-06-17 |
卷号 | 30期号:1-3页码:135-139 |
关键词 | Synthesis Hydrodesulfurization (Hds) Activity Hydrogenation (Hyd) Activity Dimolybdenum Nitride |
ISSN号 | 0920-5861 |
文献子类 | Article |
英文摘要 | Various kinds of surface area gamma-Mo2N were synthesized by a topotactic reaction between MoO3 and NH3 under relatively mild conditions. It was found that the space velocity of NH3 and the particle size of MoO3 were very important for the synthesis of high surface area gamma-Mo2N in a large batch. The percent of micropore volume in the range of 20-30 Angstrom gradually increased with increase of surface area. XRD results indicated that the intensities of diffraction peaks of high surface area gamma-Mo2N was different from those of low surface area. The measurements of catalytic activities for thiophene hydrodesulfuriztion and cyclohexene hydrogenation showed that high surface area gamma-Mo2N exhibited much higher activity than those of medium and low surface area gamma-Mo2N. Meanwhile, a hydrodesulfurizing mechanism of thiophene is proposed. |
WOS关键词 | MOLYBDENUM NITRIDE ; HYDRODENITROGENATION ; CATALYSTS ; CARBIDES |
WOS研究方向 | Chemistry ; Engineering |
语种 | 英语 |
WOS记录号 | WOS:A1996UT81000018 |
出版者 | ELSEVIER SCIENCE BV |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168062] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | CHINESE ACAD SCI,DALIAN INST CHEM PHYS,STATE KEY LAB CATALYSIS,DALIAN 116023,PEOPLES R CHINA |
推荐引用方式 GB/T 7714 | Zhang, YJ,Wei, ZB,Yan, WH,et al. Synthesis and hydrodesulfurization (HDS) and hydrogenation (HYD) activity of dimolybdenum nitride[J]. CATALYSIS TODAY,1996,30(1-3):135-139. |
APA | Zhang, YJ.,Wei, ZB.,Yan, WH.,Ying, PL.,Ji, CX.,...&Xin, Q.(1996).Synthesis and hydrodesulfurization (HDS) and hydrogenation (HYD) activity of dimolybdenum nitride.CATALYSIS TODAY,30(1-3),135-139. |
MLA | Zhang, YJ,et al."Synthesis and hydrodesulfurization (HDS) and hydrogenation (HYD) activity of dimolybdenum nitride".CATALYSIS TODAY 30.1-3(1996):135-139. |
入库方式: OAI收割
来源:大连化学物理研究所
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