Highly active polymer-anchored bimetallic palladium-based catalysts for the carbonylation of allyl halides under atmospheric pressure
文献类型：期刊论文
| 作者 | Yu, ZK; Xu, Y; Liao, SJ; Jiang, H; Yang, B; Yu, DR; Chen, H; Li, XJ |
| 刊名 | REACTIVE & FUNCTIONAL POLYMERS
 |
| 出版日期 | 1996-10-01 |
| 卷号 | 31期号:3页码:201-205 |
| 关键词 | Carbonylation Allyl Halides Polymer-anchored Palladium-based Bimetallic Catalysts Synergic Effect |
| ISSN号 | 1381-5148 |
| 文献子类 | Article |
| 英文摘要 | Highly active polymer-anchored bimetallic palladium-based catalysts (PVP-PdCl2-MY, PVP = poly(N-vinyl-2-pyrrolidone, MY = the second transition metal component) exhibit very high catalytic activity and selectivity for the carbonylation of allyl halides (CH2=CH-CH(2)X, X = Cl or Br) in toluene/dilute alcoholic-aqueous solution at 40 degrees C and atmospheric pressure in the presence of NaOH. These catalysts were prepared by the addition of a second transition metal compound to the alcoholic or aqueous solution of the polymer-anchored monometallic palladium catalyst PVP-PdCl2, i.e. FeCl3 . 6H(2)O, Co(OAc)(2) . 4H(2)O, NiCl2 . 6H(2)O, RhCl3 . 3H(2)O, or RhCl3 . H2O was added to PVP-PdCl2/EtOH, and [RuCl2(TPPTS)(2)](2), RhH(CO)(TPPTS)(3), H2IrCl6, IrH(CO)(TPPTS)(3) or IrCl(CO)(TPPTS)(2) was added to PVP-PdCl2/H2O (TPPTS = (m-NaSO3C6H4)(3)P). For allyl chloride, a remarkable synergic effect of the polymer-anchored bimetallic catalysts led to an obvious increase in the carbonylation rate and/or selectivity for the desired product, beta, gamma-butenoic acid. For allyl bromide, only a weak synergic effect was observed by the addition of RhCl3 . 3H(2)O or IrCl(CO)(TPPTS)(2) to the monometallic catalyst. |
| WOS关键词 | SODIUM-HYDROXIDE ; COMPLEXES |
| WOS研究方向 | Chemistry ; Engineering ; Polymer Science |
| 语种 | 英语 |
| WOS记录号 | WOS:A1996VR70800003 |
| 出版者 | ELSEVIER SCIENCE BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168076]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | 1.CHINESE ACAD SCI,DALIAN INST CHEM PHYS,DALIAN 116023,PEOPLES R CHINA 2.SICHUAN UNIV,DEPT CHEM,CHENGDU 610064,PEOPLES R CHINA |
| 推荐引用方式 GB/T 7714 | Yu, ZK,Xu, Y,Liao, SJ,et al. Highly active polymer-anchored bimetallic palladium-based catalysts for the carbonylation of allyl halides under atmospheric pressure[J]. REACTIVE & FUNCTIONAL POLYMERS,1996,31(3):201-205. |
| APA | Yu, ZK.,Xu, Y.,Liao, SJ.,Jiang, H.,Yang, B.,...&Li, XJ.(1996).Highly active polymer-anchored bimetallic palladium-based catalysts for the carbonylation of allyl halides under atmospheric pressure.REACTIVE & FUNCTIONAL POLYMERS,31(3),201-205. |
| MLA | Yu, ZK,et al."Highly active polymer-anchored bimetallic palladium-based catalysts for the carbonylation of allyl halides under atmospheric pressure".REACTIVE & FUNCTIONAL POLYMERS 31.3(1996):201-205. |
入库方式： OAI收割
来源：大连化学物理研究所
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