Transformation of cyclopentanone into cyclopentanethiol over a sulfided CoMo/Al2O3 catalyst
文献类型:期刊论文
作者 | Wang, J; Lemberton, JL; Li, WZ; Perot, G |
刊名 | CATALYSIS LETTERS
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出版日期 | 1996 |
卷号 | 42期号:1-2页码:81-85 |
关键词 | Cyclopentanone Cyclopentanethiol Sulfide Catalysts Como/al2o3 |
ISSN号 | 1011-372X |
文献子类 | Article |
英文摘要 | The transformation of cyclopentanone in the presence of H2S/H-2 was investigated at atmospheric pressure over a sulfided CoMo/Al2O3 catalyst. The main reaction products were cyclopentanethiol and cyclopentene, the relative amounts of which depended on the reaction temperature and on the H2S to cyclopentanone molar ratio. The best results were obtained at 220 degrees C, with a 2.5 H2S to cyclopentanone molar ratio: under these conditions, the cyclopentanethiol molar selectivity remained at about 90%, in a range of cyclopentanone conversion of 10-70%. |
WOS关键词 | HYDRODENITROGENATION ; ACIDITY |
WOS研究方向 | Chemistry |
语种 | 英语 |
WOS记录号 | WOS:A1996VV98000012 |
出版者 | BALTZER SCI PUBL BV |
源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168080] ![]() |
专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
作者单位 | 1.UNIV POITIERS,LACCO,URA CNRS 350,F-86022 POITIERS,FRANCE 2.CHINESE ACAD SCI,DALIAN INST CHEM PHYS,DALIAN 116023,PEOPLES R CHINA |
推荐引用方式 GB/T 7714 | Wang, J,Lemberton, JL,Li, WZ,et al. Transformation of cyclopentanone into cyclopentanethiol over a sulfided CoMo/Al2O3 catalyst[J]. CATALYSIS LETTERS,1996,42(1-2):81-85. |
APA | Wang, J,Lemberton, JL,Li, WZ,&Perot, G.(1996).Transformation of cyclopentanone into cyclopentanethiol over a sulfided CoMo/Al2O3 catalyst.CATALYSIS LETTERS,42(1-2),81-85. |
MLA | Wang, J,et al."Transformation of cyclopentanone into cyclopentanethiol over a sulfided CoMo/Al2O3 catalyst".CATALYSIS LETTERS 42.1-2(1996):81-85. |
入库方式: OAI收割
来源:大连化学物理研究所
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