Dehydrogenation and aromatization of methane in the absence of oxygen on Mo/HZSM-5 catalysts before and after NH4OH extraction
文献类型：期刊论文
| 作者 | Xu, Y; Liu, W; Wong, ST; Wang, LS; Guo, XX |
| 刊名 | CATALYSIS LETTERS
 |
| 出版日期 | 1996 |
| 卷号 | 40期号:3-4页码:207-214 |
| 关键词 | Mo/hzsm-5 Mo Species Moo3 Crystallites Al-2(Moo4)(3) Crystallites Methane Activation Nh4oh Extraction |
| ISSN号 | 1011-372X |
| 文献子类 | Article |
| 英文摘要 | Mo/HZSM-5 catalysts show good catalytic reactivity in the absence of oxygen for the dehydrogenation and aromatization of methane at 973 K. The active Mo species were investigated by combining catalytic studies on Mo/HZSM-5 catalysts before and after NH4OH extraction with XRD, BET, NH3-TPD and TPR analysis. The XRD patterns show that Mo species are well dispersed on the zeolite surface. The specific surface areas decrease with increasing Mo loading but they can be restored to a large extent by NH4OH extraction. NH3-TPD results suggest that the Mo species prefer to deposit on the strong acid sites of HZSM-5 zeolite. TPR profiles show that there is a kind of Mo species which is easily reduced. No TPR peaks could be obviously observed if the Mol HZSM-5 catalysts were extracted by NH4OH solution. The results of NH4OH extraction experiment and other relevant characterization studies suggest that there are several kinds of Mo species deposited on the surface. By referring to the Mo species on Al2O3 supported MoO3 samples, we propose that the dissolvable Mo species in NH4OH solution are MoO3 crystallites and their aggregates in octahedral coordination, while the unsoluble Mo species mainly are Al-2(MoO4)(3) and MoO42- in tetrahedrally coordinated form. The catalytic performance of Mo/HZSM-5 catalysts before and after NH4OH extraction illustrates that Mo species in small MoO3 crystallites with octahedral coordination form are active for methane activation in the absence of oxygen on Mo/HZSM-5 catalysts, while Mo species in tetrahedrally coordinated form is less active for the reaction. |
| WOS关键词 | ALUMINA CATALYSTS ; CONVERSION ; AROMATICS ; BEHAVIOR ; ZEOLITES |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:A1996VE92300013 |
| 出版者 | BALTZER SCI PUBL BV |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168104]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 通讯作者 | Xu, Y |
| 推荐引用方式 GB/T 7714 | Xu, Y,Liu, W,Wong, ST,et al. Dehydrogenation and aromatization of methane in the absence of oxygen on Mo/HZSM-5 catalysts before and after NH4OH extraction[J]. CATALYSIS LETTERS,1996,40(3-4):207-214. |
| APA | Xu, Y,Liu, W,Wong, ST,Wang, LS,&Guo, XX.(1996).Dehydrogenation and aromatization of methane in the absence of oxygen on Mo/HZSM-5 catalysts before and after NH4OH extraction.CATALYSIS LETTERS,40(3-4),207-214. |
| MLA | Xu, Y,et al."Dehydrogenation and aromatization of methane in the absence of oxygen on Mo/HZSM-5 catalysts before and after NH4OH extraction".CATALYSIS LETTERS 40.3-4(1996):207-214. |
入库方式： OAI收割
来源：大连化学物理研究所
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