Theoretical investigation on the new type two-dimensional packed-capillary column GC system - Effect of the column conditions on retention time and peak spreading
文献类型：期刊论文
| 作者 | Zhang, WB; Xu, GW; Shi, JJ; Zhang, YK; Lu, PZ |
| 刊名 | CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE
 |
| 出版日期 | 1996-03-01 |
| 卷号 | 17期号:3页码:367-372 |
| 关键词 | Gas Chromatography Packed-capillary Column Two-dimensional Gc System Retention Time Peak Spreading |
| ISSN号 | 0251-0790 |
| 文献子类 | Article |
| 英文摘要 | In this paper, the first moments of the peaks eluted from a two-dimensional packed-capillary column GC system were derivde by means of chromatographic dynamics, Based on this expression, the effect of the precolumn temperature, the precolumn pressure and the split ratio on the retention time and the peak spreading were discussed, The results showed that split stream was a bridge between the main column and the precolumn, the split ratio was an important factor affecting the retention time and the peak spreading, Because the retention period of the solute in precolumn was shorter, the effect of the change of the precolumn condition on retention time was smaller if the main column condition was,fixed, The higher the temperature of precolumn and the more narrow the peak, and the pead profile could be improved in a regular scope by the change of the split ratio between the two column. In accordance with the relationship between the main column and precolumn, some special rules were observed in the two-dimensional packed-capillary column GC system. |
| WOS研究方向 | Chemistry |
| 语种 | 英语 |
| WOS记录号 | WOS:A1996UB83900008 |
| 出版者 | HIGHER EDUCATION PRESS |
| 源URL | [http://cas-ir.dicp.ac.cn/handle/321008/168134]  |
| 专题 | 大连化学物理研究所_中国科学院大连化学物理研究所 |
| 作者单位 | CHINESE ACAD SCI,DALIAN INST CHEM PHYS,DALIAN CHROMATOG R&D CTR CHINA,DALIAN,PEOPLES R CHINA |
| 推荐引用方式 GB/T 7714 | Zhang, WB,Xu, GW,Shi, JJ,et al. Theoretical investigation on the new type two-dimensional packed-capillary column GC system - Effect of the column conditions on retention time and peak spreading[J]. CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,1996,17(3):367-372. |
| APA | Zhang, WB,Xu, GW,Shi, JJ,Zhang, YK,&Lu, PZ.(1996).Theoretical investigation on the new type two-dimensional packed-capillary column GC system - Effect of the column conditions on retention time and peak spreading.CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE,17(3),367-372. |
| MLA | Zhang, WB,et al."Theoretical investigation on the new type two-dimensional packed-capillary column GC system - Effect of the column conditions on retention time and peak spreading".CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE 17.3(1996):367-372. |
入库方式： OAI收割
来源：大连化学物理研究所
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